Dear Jason.  

Life and Chemistry are very complicated, but perseverance and flexibility will 
usually find an answer.

Thanks for the details,

Tom Reed

Dr Thomas B Reed
President, The Biomass Energy Foundation
www.Woodgas.com

On Jul 13, 2011, at 5:37 PM, Jason Stewart <[email protected]> wrote:

> Hi Tom,
> 
> I hate to post here too often as I am just a babe in gasification terms.
> 
> I passed the comment on thermite welding because I spent 3 months using the 
> technique to weld the copper tails onto the aluminium buzzwork for the 
> aluminium smelting cells. This was to distribute 96,000Amps at 4V at the 
> Tiwai Point Aluminium Smelter.
> 
> The thermite mix was aluminium and copper oxide. This required a staged start 
> with two different compounds to bring the temperature of the aluminium up to 
> a point where it destabilised and ignited. About 2 seconds at over 2000° the 
> molten copper would melt through the copper retaining discs and drop through 
> into the mold. 
> 
> I have no doubt you understand the chemistry better than I. What we were able 
> to achieve was to take the CADWELD training from the English engineer and 
> increase their expected output by 250% from 8 welds per two man team per day, 
> to 20. We actually did that by lunch time, but it was getting embarrassing 
> for them so we dithered around in the afternoons. At the same time we halved 
> the expected failure rate:)
> 
> Kind Regards
> 
> Jason Stewart
> 
> On Wed, Jul 13, 2011 at 11:21 PM, Thomas Reed <[email protected]> wrote:
> Dear Mark and all
> 
> Thermite welding is usually based on Mg, not Aluminum, but I presume a 
> properly prepared aluminum powder with minimal oxide skin could be used.
> 
> Tom Reed
> 
> Dr Thomas B Reed
> President, The Biomass Energy Foundation
> www.Woodgas.com
> 
> On Jul 12, 2011, at 11:32 PM, Jason Stewart <[email protected]> wrote:
> 
>> Haha, you are then set up for thermite welding.
>> 
>> On Wed, Jul 13, 2011 at 2:59 PM, Mark E. Ludlow <[email protected]> wrote:
>> Dr. Tom,
>> 
>> Can one hammer mill->ball mill the Al into a powder and burn it directly 
>> (stand back!)?
>> 
>> Mark
>> 
>>  
>> 
>> From: [email protected] 
>> [mailto:[email protected]] On Behalf Of Thomas 
>> Reed
>> Sent: Tuesday, July 12, 2011 5:53 PM
>> 
>> 
>> To: Discussion of biomass pyrolysis and gasification; Art Krenzel
>> Cc: [email protected]
>> Subject: Re: [Gasification] CONSERVATION OF ENERGY
>>  
>> 
>> PS. 
>> 
>>  
>> 
>> According to my book, THE FREE ENERGY OF BINARY COMPOUNDS (available at 
>> Woodgas.com)
>> 
>>  
>> 
>> The Enthalpy of combustion of Al 
>> 
>>  
>> 
>> Al + 3/2 O2 ==> 1/2 Al2O3.   Delta H (C) = 178 kcal/mole = 745 kJ/mole.  The 
>> MW of Al is 27, so this is 27.6 kJ/g or 12,527 kJ/ lb.  1 kW hr is 3.8 MJ, 
>> so this is 3.3 kW hr/lb. 
>> 
>>  
>> 
>> Well worth capturing.
>> 
>>  
>> 
>> Tom Reed
>> 
>> 
>> Dr Thomas B Reed
>> 
>> President, The Biomass Energy Foundation
>> 
>> www.Woodgas.com
>> 
>> 
>> On Jul 12, 2011, at 7:51 PM, GF <[email protected]> wrote:
>> 
>>  
>> 
>>     
>> 
>> The other day I posted an article on this site concerning:
>> 
>> Cornish Hydrogen Generator. Keelynet,  which describes a method of converting
>> 
>> Aluminum into its oxide and in the process cracks water, freeing up hydrogen 
>> for use as fuel for a light car.
>> 
>> By all accounts, using this gas in the place of any other fuel.
>> 
>> Distances and the amount of metal used in this attainment were mentioned.
>> 
>> I was hoping for a reaction from one of the many “Energy Economists”
>> 
>> Who lurk on this site, to respond with negative information regarding the 
>> impracticality and waste fullness of such a process?
>> 
>> I believe there is a large following on this site who are interested in 
>> obtaining electrical power using renewable energy, derived from carbon 
>> neutral sources.
>> 
>> They might question the economics and ethics of using a refined ore as fuel.
>> 
>> Instead of chopping down oxygen producing vegetation. 
>> 
>> In this respect I am a nonconformist. I believe most Aluminum is produced by 
>> Hydro electric power and, so the CO2 is not in the equation.
>> 
>> My second comment is harnessing a “free” supply of high temperature heat 
>> which is emitted from most Ice’s in the form of “Hot Exhaust”.
>> 
>> This is the place to install a reactor capable of converting beer cans into 
>> hydrogen as not too much energy would be needed to complete the reaction. 
>> Bubbling super heated steam through a molten bath of AL would give pure 
>> hydrogen.
>> 
>> No tar, and the ash is a hot commodity
>> 
>>  
>> 
>> The real question is: how much energy is locked up in a pound of AL
>> 
>>  
>> 
>> gfwhell
>> 
>>  
>> 
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>> 
>> 
>> 
>> -- 
>> Kind Regards
>> 
>> Jason Stewart
>> 3 Opahi Bay Road,
>> RD3
>> Warkworth
>> 09 4220054
>> 
>> 
>> 
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> 
> 
> 
> -- 
> Kind Regards
> 
> Jason Stewart
> 3 Opahi Bay Road,
> RD3
> Warkworth
> 09 4220054
> 
> 
> 
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