*Urea pollution can trigger ocean algae to produce a deadly toxin called
domoic acid, scientists have discovered.*

Note that this does not mean *will *create such toxins in all places, in all
modes of fertilization. Issues like this raise research and monitoring
concerns but do not represent a fundamental challenge to the concept of urea
fertilization.

( That is not to say that there are not more fundamental challenges ... lack
of scalability, phosphate utilization, low areal densities of carbon
storage, etc. )

___________________________________________________
Ken Caldeira

Carnegie Institution Dept of Global Ecology
260 Panama Street, Stanford, CA 94305 USA

[email protected]; [email protected]
http://dge.stanford.edu/DGE/CIWDGE/labs/caldeiralab
+1 650 704 7212; fax: +1 650 462 5968



On Fri, Dec 12, 2008 at 8:28 AM, Dan Whaley <[email protected]> wrote:

>
> Not sure if this was posted before...
>
>
> Published online 27 October 2008 | Nature | doi:10.1038/news.2008.1190
>
> News
> Urea pollution turns tides toxic
>
> Kamikaze gulls that inspired Hitchcock's The Birds may have been
> doomed by
> leaky septic tanks.
>
> Amy Coombs
> The BirdsRun, Tippi, run!UNIVERSAL / THE KOBAL COLLECTION
>
> Urea pollution can trigger ocean algae to produce a deadly toxin
> called
> domoic acid, scientists have discovered.
>
> The research may help explain several mass animal deaths, including a
> historic bird stranding event thought to have inspired Alfred
> Hitchcock's
> horror film The Birds.
>
> Raphael Kudela, an ocean scientist at the University of California,
> Santa
> Cruz, and his team made the discovery after studying a form of sea
> algae
> called Pseudo-nitzschia australis. Although the algae's blooms are
> normally
> benign, they have long been known to sometimes begin making domoic
> acid.
>
> Much like the kamikaze gulls portrayed in the 1963 horror film,
> animals
> poisoned by domoic acid have erratic behaviour patterns. On 18 August,
> 1961,
> residents in the town of Capitola, California, awoke to find sooty
> shearwaters slamming into their rooftops, and their streets covered
> with
> dead birds. According to the local paper, Alfred Hitchcock ‹ who lived
> a few
> miles away ‹ requested news copy to use as "research material for his
> latest
> thriller", which was based on Daphne du Maurier's 1952 short story,
> The
> Birds.
> Serial killer
>
> Although researchers can only speculate that domoic acid caused this
> historic event, modern toxicologists have conclusively linked the
> toxin to
> more recent cases. In 1987 contaminated shellfish poisoned 100 people
> on
> Prince Edward Island in Canada, killing three and causing many cases
> of
> amnesia. In 1998, 400 disoriented sea lions died along California's
> central
> coast ‹ domoic acid was traced back to contaminated fish that swam
> through a
> toxic bloom before being eaten by the sea lions. "Every few years
> there is a
> big outbreak that causes otters, pelicans or sea-lion deaths," says
> Kudela.
>
> "The acid binds very tightly to surface receptors on excitatory
> neurons,
> which makes it hard for the cells to switch off," says Melissa Miller,
> a
> veterinarian at the California Department of Fish and Game in Santa
> Cruz.
> While the toxin doesn't make animals homicidal, the brain damage it
> causes
> accounts for the strange behavior patterns that precede death, says
> Miller.
>
> Human pollution was thought to play a role, but researchers were never
> able
> to identify which contaminant causes P. australis to start producing
> domoic
> acid. "It's definitely a combination of factors, which makes it hard
> to show
> a cause and effect relationship," says Kudela.
>
> So he and his colleagues tested a range of chemicals found in
> fertilizers,
> including nitrate, ammonium and urea, to determine their effects on
> the
> algae. Urea was the only chemical that increased domoic-acid
> production. In
> cases where the plankton mysteriously began making low levels of the
> toxin
> in clean water, adding urea nearly doubled production.
>
> After taking water samples off the coast of California, they also
> found that
> urea concentrations in Monterey Bay and San Francisco Bay were high
> enough
> to account for some recent harmful algal bloom events.
> Human cause
>
> Urea isn't commonly found in agricultural fertilizers, but it is
> present in
> many garden products. Sewage-treatment plants tested as part of
> Kudela's
> study did not discharge much urea, but leaky septic tanks have been
> known to
> dump urea into the Chesapeake Bay and the Gulf of Mexico. "Marine
> animals
> release small amounts of urea, but the pollution problem is almost
> entirely
> human caused," says Kudela. The findings will appear in the November
> issue
> of Harmful Algae.1,2
>
> "This work directly links human activities to the hundreds of marine
> mammal
> mortalities resulting from exposure to domoic acid," says Frances
> Gulland,
> director of veterinary science at the Marine Mammal Center in
> Sausalito,
> California.
>
> Although there is no way to know for sure if urea caused the famous
> incident
> that inspired The Birds, Kudela says the pollutant was probably
> leaching
> into the ocean at the time. "There was a lot of new development back
> then,
> with many unregulated septic tanks going in," he says.
>
> Kudela now plans to look for other chemical factors that may cause the
> P.
> australis tides to turn toxic.
>
>    *
>      References
>         1. Cochlan, W. P., Herndon, J. & Kudela, R. M., Harmful Algae
> doi:10.1016/j.hal.2008.08.008 (2008).
>         2. Kudela, R. M., Lane, J. Q. & Cochlan, W. P., Harmful Algae
> doi:10.1016/j.hal.2008.08.019 (2008).
>
>
> >
>

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