I have previously mentioned sequestration through mineralization as a
promising element response to alarms about CO2.  It isn't free, but it may
well be the most permanent capture mechanism.  Here's a blurb about the
formations that are available for use in the US.  Keith, this is the kind of
work I mentioned to you by email recently.

d.

Contact: Kevin Krajick
[email protected]
212-854-9729
The Earth Institute at Columbia University <http://www.earth.columbia.edu/>
Scientists target East Coast rocks for CO2 storage Power plants might pipe
emissions under seabed
<http://www.eurekalert.org/multimedia/pub/19300.php?from=151580>

*IMAGE:* <http://www.eurekalert.org/multimedia/pub/19300.php?from=151580> Left:
Basalts inland (hatched) and offshore (grey) in the New York area may be
useful for storing CO2. Right: An even larger formation occurs around South
Carolina and Georgia. Squares...
Click here for more
information.<http://www.eurekalert.org/multimedia/pub/19300.php?from=151580>

     Scientists say buried volcanic rocks along the heavily populated coasts
of New York, New Jersey and New England, as well as further south, might be
ideal reservoirs to lock away carbon dioxide emitted by power plants and
other industrial sources. A study this week in the *Proceedings of the
National Academy of Sciences* outlines formations on land as well as
offshore, where scientists from Columbia University's Lamont-Doherty Earth
Observatory say the best potential sites may lie.

Underground burial, or sequestration, of globe-warming carbon dioxide is the
subject of increasing study across the country. But up till now, research in
New York has focused on inland sites where plants might send power-plant
emissions into shale, a sedimentary rock that underlies much of the state.
Similarly, a proposed coal-fired plant in Linden, N.J. would pump liquefied
CO2 offshore into sedimentary sandstone. The idea is controversial because
of fears that CO2 might leak. By contrast, the new study targets basalt, an
igneous rock, which the scientists say has significant advantages.

Some basalt on land is already well known and highly visible. The vertical
cliffs of the Palisades, along the west bank of the Hudson River near
Manhattan, are pure basalt, and the rocks, formed some 200 million years
ago, extend into the hills of central New Jersey. Similar masses are found
in central Connecticut. Previous research by Lamont scientists and others
shows that carbon dioxide injected into basalt undergoes natural chemical
reactions that will eventually turn it into a solid mineral resembling
limestone. If the process were made to work on a large scale, this would
help obviate the danger of leaks.

The study's authors, led by geophysicist David S. Goldberg, used existing
research to outline more possible basalt underwater, including four areas of
more than 1,000 square kilometers each, off northern New Jersey, Long Island
and Massachusetts. A smaller patch appears to lie more or less under the
beach of New Jersey's Sandy Hook, peninsula, opposite New York's harbor and
not far from the proposed plant in Linden. The undersea formations are
inferred from seismic and gravity measurements. "We would need to drill them
to see where we're at," said Goldberg. "But we could potentially do deep
burial here. The coast makes sense. That's where people are. That's where
power plants are needed. And by going offshore, you can reduce risks."
Goldberg and his colleagues previously identified similar formations off the
U.S. Northwest.

Goldberg said the undersea formations are potentially most useful, for
several reasons. For one, they are deeper—an important factor, since CO2
pressurized into a liquid would have to be placed at least 2,500 feet below
the surface for natural pressure to keep it from reverting to a gas and
potentially then making its way back to the surface. The basalts on land are
relatively shallow, but those at sea are covered not only by water, but
hundreds or thousands of feet of sediment, and appear to extend far below
the seabed. In addition to providing pressure, sediments on top would form
impermeable caps, said Goldberg. The basalts are thought to contain porous,
rubbly layers with plenty of interstices where CO2 could fit, simply by
displacing seawater. On land, by contrast, there are concerns that drilling
and injection could disturb aquifers or otherwise get in the way of
neighbors. The scientists estimate that just the small Sandy Hook basin may
contain about seven cubic kilometers of the rock, with enough pore space to
hold close to a billion tons of CO2—the equivalent of the emissions from
four 1-billion-watt coal-fired plants over 40 years.

"The basalt itself is very reactive, and in the end, you make limestone,"
said coauthor Dennis Kent, who is also at Rutgers University. "It's the
ultimate repository."

Previous research has identified other areas of basalt sprinkled along the
Appalachians. The largest mass of all appears to extend offshore of Georgia
and South Carolina, as well as inland. This coast also is populous, and
would make a good target, said Goldberg. "The next step would be to get some
exploratory surveying and drilling going," he said. The paper suggests a
half-dozen spots around New York including the Sandy Hook area, and three
off South Carolina, to start with.

###

The study was also coauthored by geologist and paleontologist Paul Olsen,
who has participated in drilling the basalt inland in New Jersey.

The paper, "CO2 Sequestration in central atlantic magmatic province basalts:
Potential on-shore and off-shore reservoirs" is available from the authors
or the *Proceedings of the National Academy of Sciences* press office:
[email protected], 202-334-1310.

Author contacts:
David Goldberg [email protected] o. 845-365-8674; c. 914-548-8456
Dennis Kent [email protected] o. 845 365 8544 c. 845-558-2026
Paul Olsen [email protected] o. 845-365- 8491; c. 845-729-2434;

More information: Kevin Krajick, Senior Science Writer, The Earth Institute
[email protected] 212-854-9729

The Earth Institute, Columbia University mobilizes the sciences, education
and public policy to achieve a sustainable earth. Through interdisciplinary
research among more than 500 scientists in diverse fields, the Institute is
adding to the knowledge necessary for addressing the challenges of the 21st
century and beyond. With over two dozen associated degree curricula and a
vibrant fellowship program, the Earth Institute is educating new leaders to
become professionals and scholars in the growing field of sustainable
development. We work alongside governments, businesses, nonprofit
organizations and individuals to devise innovative strategies to protect the
future of our planet. www.earth.columbia.edu. Lamont-Doherty Earth
Observatory, a member of The Earth Institute, is one of the world's leading
research centers seeking fundamental knowledge about the origin, evolution
and future of the natural world. More than 300 research scientists study the
planet from its deepest interior to the outer reaches of its atmosphere, on
every continent and in every ocean. From global climate change to
earthquakes, volcanoes, nonrenewable resources, environmental hazards and
beyond, Observatory scientists provide a rational basis for the difficult
choices facing humankind in the planet's stewardship. www.ldeo.columbia.edu


-- 
David W. Schnare
Center for Environmental Stewardship

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