Further to Mike's comments:

 

When methane seeps into sea water and gets dissolved, it gets attacked by 
methanogenic bacteria that cosumes this to carbon dioxide. The carbon dioxide 
then dissolves again into water. However, there are about 22,000 methane 
clathrate explosion craters in the Arctic. The largest methane escape crater on 
the sea floor measures over 750 km2 in area.

 

Royal Society's science book of the year award for 2008 was awarded to Mark 
Lynas' "The Six Degrees" which refers to the methane clatrate explosion sites 
in the Arctic sea beds. 

 

The off-shore methane craters have resulted from violent gas bursts of methane. 
As methane itself is soluble to a sea water in a limited degree, a gradual 
build up of carbon dioxide is often required to necessitate the nucleation of 
dissolved gases.

 

Carbon dioxide is dissolving in cold and deep waters sometimes 5 times of the 
volume of water or more, methane is dissolving considerably too, but not nearly 
as much as carbon dioxide. When outgassing event and methane clathrate 
explosions do occur, methane that has been converted to carbon dioxide acts as 
the active ingredient of gas nucleation.

 

Michel Halbwachs has successfully neutralised three deep water methane/carbon 
dioxide laden deepwater pockets that have been nucleating (or pose major risk 
of gas nucleation). He has three successful projects under management on 
controlled outgassing of highly dissolved deep water pockets that can cause 
fatalities if gas is not leaked out.

 

As methane clathrates dissolve in innumerable sites across deep Arctic lakes 
and coastal deep water pockets (that lack adequate water circulation), as the 
methane leaks out and gets converted to carbon dioxide, it builds up and 
eventually starts to sizzle out (like champagne) when there are disturbances in 
the vertical water column, or excess heating.

 

These can also be stirred and triggered by vessels traveling over and can be 
extremely dangerous due to density of nucleating water being much lower due to 
its high, nucleated, foamy gas content. When the carbon dioxide sizzles out, 
the methane comes out with it.

 

The high carbon dioxide content of water may also shut down some methanogenic 
bacteria, this effectively stopping further conversion of methane into carbon 
dioxide. Thus, the proportion of gas dissoleved will eventually consist high 
volumes of methane as well.

 

I have also been in touch with some scientists who believe that there were 
recently a huge methane explosion resulting from the conical deep water basin 
of Lake Cheko, where a sub lake bed may have collapsed due to melting of 
permafrost layer that was retaining a gas field. The lake and trespassing river 
may have fallen into the cavity of gas field triggering huge methane explosion 
3-5 miles above nearby Tunguska forest in spring 1908. This explosion killed 
and injured about half a dozen people due to its remoteness. Microdiamonds and 
molten rock materials have been discovered. The standard idea is that it was a 
meteorite impact (a bolide fire ball) rather than an on-shore methane explosion.

 

For the COP15/COP16 intermediate summit at Copababamba, I yesterday received 
petition to put forward from the First Nations' as some ancient first nations 
of the Americas recall seeing these immense fireballs, what they say, at the 
end of ice age, perhaps in Beringia when they were forced to move out as sea 
levels rose which area is near to the methane explosions and migrants came 
roughly via the same area (North East Coast of Siberia) as Mark Lynas', Euan 
Nisbet and others reported findings of sea floor methane escape craters. 

 

Back in July 2008 there were also huge explosion on the North West Passage, 
Nunavut, Canada, about ten days to two weeks after the NW passage cleared 
itself off sea ice, which was second consecutive summer when the area was sea 
ice free. The sound were heard hundreds of miles away and whales were spotted 
moving away from the area. 


Therefore, we need to keep in mind and search for the still deep water pockets 
or areas that may be excessively accummulating methane and carbon dioxide when 
permafrost soils and methane clathrated sea beds are melting.

 

If you know of any extremely carbon dioxide and methane laden sites (still deep 
water pockets) please contact Michel Halwachs who has been successfully 
contracted to defuse these. It would also make sense to controllably neutralise 
some of them and burn nucleating methane-carbon dioxide mixtures rather than 
letting them GHGs to go for birds.

 

Wint kind regards,

 

Veli Albert Kallio

 


Date: Sun, 7 Mar 2010 09:55:56 -0500
Subject: Re: [geo] Methane - time for realism
From: [email protected]
To: [email protected]; [email protected]
CC: [email protected]

While I wholeheartedly agree that methane is a critical issue, it would sure be 
nice if they got the facts right.

Consider this paragraph: “Dr. Shakhova said that undersea methane ordinarily 
undergoes oxidation as it rises to the surface, where it is released as carbon 
dioxide. But because water over the shelf is at most about 50 meters deep, she 
said, the gas bubbles to the surface there as methane. As a result, she said, 
atmospheric levels of methane over the Arctic are 1.85 parts per million, 
almost three times as high as the global average of 0.6 or 0.7 parts per 
million. Concentrations over the shelf are 2 parts per million or higher.”

It is simply not the case that the concentration over much of the globe is 
currently 0.6 or 0.7 parts per million. That may well have been the 
preindustrial concentration that was being referred to, and if that is the 
case, that correction is needed. Alternatively, they should report the global 
average concentration as roughly 1.6 to 1.7 parts per million, as is clearly 
shown in the global observations (see 
http://instaar.colorado.edu/sil/images/ch4rug_490px.jpg ).  

Mike


On 3/5/10 5:11 PM, "John Nissen" <[email protected]> wrote:



http://www.worldchanging.com/archives/011011.html 

Methane Melt: The Most Important Story You Don't Follow 

Alex Steffen <http://www.worldchanging.com/bios/alex.html> , 5 Mar 10

We've written before about the danger that climate change will lead to the 
thawing and release of methane frozen on the ocean floor, and indeed the 
worrisome news that some scientists were observing patches of Arctic sea 
foaming with gas bubbles from "methane chimneys" rising from the sea floor 
<http://www.worldchanging.com/archives/008702.html> . 

Now, researchers in Alaska have found a similar process underway 
<http://www.nytimes.com/2010/03/05/science/earth/05methane.html?em> : 


Natalia Shakhova, a scientist at the university and a leader of the study, said 
it was too soon to say whether the findings suggest that a dangerous release of 
methane looms. In a telephone news conference, she said researchers were only 
beginning to track the movement of this methane into the atmosphere as the 
undersea permafrost that traps it degrades. 

But climate experts familiar with the new research reported in Friday’s issue 
of the journal Science that even though it does not suggest imminent climate 
catastrophe, it is important because of methane’s role as a greenhouse gas. 
Although carbon dioxide is far more abundant and persistent in the atmosphere, 
ton for ton atmospheric methane traps at least 25 times as much heat. 
 
Until recently, undersea permafrost has been little studied, but work so far 
shows it is already sending surprising amounts of methane into the atmosphere, 
Dr. Shakhova and other researchers are finding. 
 
Last year, scientists from Britain and Germany reported that they had detected 
plumes of methane rising from the Arctic seabed in the West Spitsbergen area, 
north of Scandinavia. At the time, they said they had begun their work hoping 
to gain data to predict future emissions and had not expected to find evidence 
that the process was under way. 
 
It is “indispensable” to keep track of methane in the region, Martin Heimann of 
the Max Planck Institute in Germany said in a commentary accompanying the 
Science report. So far, Dr. Heimann wrote, methane contributions from Arctic 
permafrost have been “negligible.” He added: “But will this persist into the 
future under sustained warming trends? We do not know.” 
 
In an e-mail message, Euan G. Nisbet of the University of London, an expert on 
atmospheric methane, said the situation “needs to be watched carefully.” 
 
Atmospheric concentrations of methane have more than doubled since 
pre-industrial times, Dr. Heimann wrote. Most of it comes from human activities 
including energy production, cattle raising and the cultivation of rice. But 
about 40 percent is natural, including the decomposition of organic materials 
in wetlands and frozen wetlands like permafrost. 
 
Dr. Shakhova said that permafrost in the East Siberian Arctic Shelf, peat land 
that flooded as sea levels rose after the last ice age, is degrading in part 
because runoff from rivers that feed the Arctic Ocean is warmer than in the 
past. 
 
She estimated that annual methane emissions from the East Siberian Arctic Shelf 
total about seven teragrams. (A teragram is 1.1 million tons.) By some 
estimates, global methane emissions total about 500 teragrams a year. 
 
Dr. Shakhova said that undersea methane ordinarily undergoes oxidation as it 
rises to the surface, where it is released as carbon dioxide. But because water 
over the shelf is at most about 50 meters deep, she said, the gas bubbles to 
the surface there as methane. As a result, she said, atmospheric levels of 
methane over the Arctic are 1.85 parts per million, almost three times as high 
as the global average of 0.6 or 0.7 parts per million. Concentrations over the 
shelf are 2 parts per million or higher.

A huge release of one-frozen methane is (potentially) almost the definition of 
a feedback loop <http://www.worldchanging.com/archives/010802.html> , perhaps 
even a tipping point into runaway climate change. 

Luckily, we're not there yet. Scientists have been very clear to say that while 
these field observations are surprising and disturbing, they do not yet 
indicate a catastrophe. We need to wait for more data to figure out if it's 
time to panic yet. 

In the meantime, we need to focus even more strongly on four solution spaces: 

1) Getting to a zero net emissions 
<http://www.worldchanging.com/archives/007879.html> economy as quickly as 
possible. It's very clear now that we can do this at a net gain for society, 
with more (and more wide-spread) prosperity for most people, and that it's 
largely the opposition of entrenched interests that's preventing us from making 
huge strides forward: this needs to change. 

2) Implementing climate-adaptive ecological restoration, safeguarding  
<http://www.worldchanging.com/archives/004253.html> ecosystem services and 
researching  <http://www.worldchanging.com/archives/007126.html> soil carbon 
sequestration <http://www.worldchanging.com/local/canada/archives/008992.html> 
and other practices that have multiple benefits while pulling greenhouse gasses 
from the air. We need to be helping the planet's natural systems heal towards 
resilience as much as we possibly can. 

3) Engaging in a stronger and more realistic debate about geoengineering, its 
limits and its politics <http://www.worldchanging.com/archives/008364.html> , 
especially since news of potential tipping points always accelerates calls for 
geoengineering research, even deployment. Geoengineering's main use in the 
climate debate at the moment is as a propaganda tool by those seeking to stall 
action on emissions reduction 
<http://www.worldchanging.com/archives/009784.html> ; that doesn't mean that we 
don't need to discuss what mega-scale answers might be possible should we find 
tipping points sliding past more quickly than we feared. 

4) Building psychological resilience 
<http://www.worldchanging.com/archives/007906.html> in the face of huge and 
alarming planetary changes. News like this is disturbing. We need to find ways, 
as a culture, as communities and as individuals, to understand disturbing 
changes without losing our balance. Psychologically wrecked people are no good 
to themselves, others or the planet. We need to promote the capacity to be 
healthy and happy despite monumental challenges.



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