Hi Steven,

I think what needs to be decided is the approach:

1) are we trying to address spot-like emissions, or,
2) methane haze arising smoothly from vast area of sea bed.

No. 1 can be addressed by a cupola-like hood over the spot from where the gases 
are removed
No. 2 can be addressed by a slightly V-shapedly folded straps of plastic where 
gas accummulates to the tip of upside down V-fold and steams towards the rising 
end of strap where it is collected. I think flatbed sheet probaly oozes gas out 
from over the edges, or one ends up with a controured sheet of multiple gas 
bubbles; this becomes increasingnly unstable system as gas accummulates. I 
favour passive systems where gas constantly streams upwards to the collection 
point. I also think that I roll could be unwound from the back of ship.

However, just 1 km2 area with 10 metre strap plastic would require 100 km of 
sailing back and forth before all is covered. If 100 km x 100 km box was 
covered from ESAS by sheet 100,000 km of 100 metre strap would be needed. 
Anoxic conditions can be addressed by say using 2kW Mixox units that could blow 
1,000,000 m3 of oxygenated air under the plastic sheet to aerate the plastic 
covered ocean. Mixox would suck oxygen rich surface air and blow it through 
tube to beneath the plastic sheet. As methane bubbles are lighter than even 
oxygenated and less saline surface air, the bubbles would still rise normally 
through the treated water until they reach the collecting sheet.

We proposed with Matti Lappalainen at the World Water Week in 2006 to oxygenate 
the Amazon river estuary during the low oxygen drought season with 40,000 Mixox 
units for 100 km section of Amazon in our paper "Preparing the Amazon 
Ecosystems for the Changing Climate". Mixox systems are deployed in 27 km2 sea 
floor oxygenation pilot project in the Baltic Sea in Finland and another 2.7 
km2 in Sweden to reduced the anoxic conditions arising from warmer 
temperatures, phosphathe leaks and organic material load. 

I forward this to Matti as he may have some latest results from the pilot 
projects. In the Baltic Sea anoxic conditions result mainly from phosphate, 
although organic loads and higher water temperatures (i.e. the Gulf of Bothnia 
has seen mean sea temperature to rise +6C). There is no problems of methane 
arising from the Baltic Sea's sea bed, Mixox has only been deployed to rectify 
the lack of oxygen.

I think Mixox at 1,000,000 m3 and 2 kW is right system to flush air under the 
plastic cover. Furthermore, the oxygen put under sheet will not excape it is 
either consumed by methane eating bacteria or other processes. Even mere 
aerating the sea might work to increase methane eating bacteria to reduce 
methane leak to air if there is a problematic build up of undigested methane in 
water that may start to nucleate. It could be that such water could be part 
oxygenated by Mixoox of Lappalainen, part ventilated by system developed by 
Michel Halbwachs whichever suits best for a situation; i.e. if the collection 
of gas for disposal is difficult Mixox needs only electric wire, or even solar 
panel or wind turbine to run (these have not been looked at as power points are 
not the issue in the Baltic Sea, unlike the Arctic Ocean).

The other issue is to develop some minimum/maximum values for deployment to do 
it economically and efficiently, rather than scattering equipment across vast 
areas of ocean that are poorly attended and maintained. There has to be the 
minimium value / distance to service for each spot where GHGs are leaking out 
of the melting methane clathrates. If two sites are close by, they may be 
serviced togheter, so a lower collection threshold is required. If power point 
is closer, also a lower threshold for methane caption may be required. For sea 
area methane haze minimum per area must be established as all sea floor leaks 
out some amount of methane, what is the action threshold?

Note that the large water body Mixox systems for the Baltic Sea will blow down 
much more areated water than the pilot systems.

Kind regards,

Albert


Date: Thu, 6 Oct 2011 10:44:25 +0100
From: [email protected]
To: [email protected]
CC: [email protected]; [email protected]; [email protected]; 
[email protected]; [email protected]; [email protected]; 
[email protected]; [email protected]; 
[email protected]
Subject: [geo] Re: Arctic methane workshop: 15-16 October - Methane vents



  


    
  
  
    Albert

    

    If there is a pipe connection to the underside of the plastic the
    pressure below the film will be close to atmospheric and it will be
    clamped firmly down by several bar of water pressure.   I can also 
    get some sand over the film.  

    

     I am more concerned about anoxic conditions of which I am totally
    ignorant.  Gases can come up from below.  Maybe we could get a film
    with some oxygen permeability.  But if there is oxygen there now why
    is there any methane?

    

     I was going to design for 0.15 metre per second sea bed current. 
    Would you recommend any other value?  I am working on a way to
    recover the film later.

    

    Stephen

    Emeritus Professor of Engineering Design
Institute for Energy Systems
School of Engineering
Mayfield Road
University of Edinburgh EH9  3JL
Scotland
Tel +44 131 650 5704
Mobile 07795 203 195
www.see.ed.ac.uk/~shs

    

    On 05/10/2011 18:58, Veli Albert Kallio wrote:
    
      
      
        We need to consider carefully the plastic film, this could cause
        anoxic conditions under the plastic sheet. 
        

        
        The shallow portion of Arctic Ocean is likely to develop
          large storm surges and resulting currents as ocean becomes ice
          free. Every storm surge on surface is maintained by reverse
          flow on bottom that could pile up any plastics and cause
          hazards. Funnelling can only be considered for spot like
          emissions, not if methane bubbles over large areas.
        

        
        The difficulty will be how to cope with monitoring and
          controlling if there will be thousands of sites where methane
          is collected that are sparsely distributed. Maintenance is a
          challenge.

          

          > Date: Wed, 5 Oct 2011 10:31:28 +0100

            > From: [email protected]

            > To: [email protected]

            > CC: [email protected]; [email protected];
            [email protected]; [email protected];
            [email protected]; [email protected];
            [email protected]; [email protected];
            [email protected]

            > Subject: Arctic methane workshop: 15-16 October -
            Methane vents

            > 

            > 

            > Dear Professor Westbrook,

            > 

            > Thank you for your response about the width of the
            shelf margin. 

            > Stephen Salter is working on a method using large
            plastic sheets to 

            > funnel the methane bubbling up from across an area of
            the sea bed into a 

            > concentrated stream, and then capturing it. But of
            course this 

            > funnelling can occur naturally, as one can see from the
            hundreds of 

            > underwater plumes that you have detected arising from
            the seabed of the 

            > West Spitzbergen continental margin [1]. Am I right
            that, at present, 

            > few of these plumes are reaching the surface? Is this
            because the water 

            > is sufficiently oxygenated for oxidation to occur
            within the water 

            > column? Is there a danger of this oxygen getting used
            up? But, if 

            > oxidation does continue, isn't there a danger of
            excessive ocean 

            > acidification, given the quantities of methane?

            > 

            > Do you have any suggestions for how one might deal with
            the methane 

            > rising in a plume, to minimise the various associated
            hazards: 

            > greenhouse gas warming if it reaches the surface,
            deoxidation of water 

            > making it sterile, acidification of the water
            disrupting the marine food 

            > chain that relies on shelled creatures, etc.?

            > 

            > Best wishes,

            > 

            > John

            > 

            > Tel: +44 20 8742 3170

            > Skype: john.nissen4

            > 

            > P.S. I want as much brainstorming done before the
            meeting as possible, 

            > especially to involve people who might not be able to
            attend in person.

            > 

            > [1]
            http://eprints.soton.ac.uk/64607/1/2009gl039191%2Baux.pdf

            > 

            > ---

            > 

            > On 03/10/2011 18:03, John Nissen wrote:

            > >

            > > Dear Professor Westbrook,

            > >

            > > A workshop has been arranged on the weekend 15-16
            October in Chiswick, 

            > > London W4, to see how to tackle the Arctic methane
            problem - in 

            > > particular how to prevent large quantities of
            methane reaching the 

            > > atmosphere and aggrevating global warming. For
            some years it has been 

            > > apparent that there is vast quantity of carbon
            locked up in 

            > > permafrost, which is liable to be released as
            methane as the Arctic 

            > > warms [1]. Global warming potential of methane is
            high but lifetime 

            > > is short, so the speed of discharge is very
            important to know. 

            > > Unfortunately recent evidence suggests that the
            Arctic warming is 

            > > accelerating, the Arctic Ocean could be seasonably
            ice free within a 

            > > few years, and there is already much methane
            venting taking place. 

            > > Therefore the situation appears extremely
            dangerous, and it is vital 

            > > that some plan of action is developed as quickly
            as possible. That is 

            > > the basic reason for the workshop.

            > >

            > > We had originally planned for the workshop to
            concentrate on the 

            > > methane from the East Siberian Arctic Shelf, ESAS,
            since Shakhova et 

            > > al claim that up to ~50 Gt of methane could be
            released "at any 

            > > moment" [2], e.g. if there were an earthquake (and
            the ESAS contains 

            > > an earthquake zone). However just in the last few
            days, I have seen 

            > > reports of high levels of methane in the upper
            atmosphere which could 

            > > have originated from shelf margins, and I came
            across a paper you 

            > > co-authored [3].

            > >

            > > I would be extremely grateful if you could come to
            the workshop, even 

            > > if only for part of one day (preferably Saturday
            15th), to discuss 

            > > your work on the methane from shelf margins, which
            I see is one of 

            > > your main research topics [4].

            > >

            > > One of the main contributors to the workshop is a
            brilliant engineer 

            > > and inventor, Professor Stephen Salter, who has
            some ideas for 

            > > capturing methane underwater. He needs to know the
            conditions of the 

            > > shelf margins and distribution of venting over the
            field. For 

            > > example, what is the typical width of the shelf
            margin where the vents 

            > > occur? In the paper [3], it is mentioned that 900
            Kg of methane may 

            > > be emitted per metre of length of the shelf
            margin, but over what width?

            > >

            > > Working in regions where there is sea ice is going
            to be a challenge, 

            > > so we have an expert on sea ice, Professor Peter
            Wadhams, coming to 

            > > the workshop. He is particularly concerned about
            the sea ice volume 

            > > decline, where the current trend suggests a zero
            volume for September 

            > > 2015 [5].

            > >

            > > BTW, some time ago I had asked Euan Nisbet to come
            to the workshop, 

            > > but unfortunately he is unable to attend. So I had
            been looking to 

            > > the PERGAMON project, and Jens Greinart, with his
            knowledge of natural 

            > > gas venting. It now appears that he might not be
            able to attend 

            > > either. So your experience from the PERGAMON
            project could be very 

            > > valuable at the workshop.

            > >

            > > I apologise for the extremely short notice, but I
            look forward to 

            > > hearing from you.

            > >

            > > Kind regards,

            > >

            > > John (Nissen)

            > >

            > > College House,

            > > Chiswick Mall,

            > > London W4 2PR

            > >

            > > Tel: 020 8742 3170

            > > Mob: 07890 657 498

            > >

            > > [1]
            http://www.aibs.org/bioscience-press-releases/resources/Schuur.pdf

            > >

            > > [2] Reported in
            http://en.wikipedia.org/wiki/Arctic_methane_release

            > >

            > > See also [2a]
            http://www.sciencemag.org/content/327/5970/1246.short

            > > and [2b] 

            > >
http://earth.usc.edu/ftp/lund/BERING%20SEA%20EXP%20323/Uservol/Articles%20of%20interest/Eurasian%20Basin/Shakova%20and%20Semiletov%202007.pdf

            > >

            > > [3]
            http://eprints.soton.ac.uk/64607/1/2009gl039191%2Baux.pdf

            > >

            > > [4]
            
http://www.birmingham.ac.uk/staff/profiles/gees/westbrook-graham.aspx

            > >

            > > [5]
            
http://neven1.typepad.com/.a/6a0133f03a1e37970b015433129b3e970c-popup

            > >

            > > ---

            > > [snip]

            > >

          
        
      
    
  


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