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http://www.nature.com/nclimate/journal/vaop/ncurrent/full/nclimate1528.html

Stratospheric aerosol particles and solar-radiation management : Nature
Climate Change : Nature Publishing Group

The deliberate injection of particles into the stratosphere has been
suggested as a possible geoengineering scheme to mitigate the global
warming aspect of climate change. Injected particles scatter solar
radiation back to space and thus reduce the radiative balance of Earth.
Previous studies investigating this scheme have focused primarily on
sulphuric acid particles to mimic volcanic injections of stratospheric
aerosol. However, the composition and size of volcanic sulphuric acid
particles are far from optimal for scattering solar radiation. We show that
aerosols with other compositions, such as minerals, could be used to
dramatically increase the amount of light scatter achieved on a per mass
basis, thereby reducing the particle mass required for injection. The
chemical consequences of injecting such particles into the stratosphere are
discussed with regard to the fate of the ozone layer. Research questions
are identified with which to assess the feasibility of such geoengineering
schemes.Many strategies and techniques for geoengineering Earth's climate
have been suggested1, 2. The deliberate injection of aerosols into the
stratosphere is a solar-radiation management (SRM) scheme, and has been
suggested to be affordable and have a high effectiveness compared with
other geoengineering schemes that have been suggested for mitigation of
global warming1. However, it has also been suggested that SRM has a low
associated safety compared with other geoengineering schemes, because of
its possible effects on regional climate, stratospheric ozone,
high-altitude tropospheric clouds and biological productivity1. The lower
stratosphere already contains a sulphuric acid (H2SO4) aerosol layer
produced from the oxidation of both biogenic and volcanic sulphur gases
(OCS and SO2)3, 4. In addition to H2SO4 aerosol, there are other
particulate matters of diverse origin present in the stratosphere, for
example, volcanic mineral dusts, meteoric metals/oxides, carbonaceous
material injected from aircraft operations and material transported from
the underlying tropospheric regions5. The amounts from these sources are
generally minor except in the event of major perturbations from explosive
volcanic eruptions. The mean exchange time between the lower stratosphere
and the troposphere is around 1–2 years, and submicrometre aerosols with a
low settling velocity introduced into the stratosphere reside there for
several years. Significant global surface cooling through the generation of
stratospheric H2SO4 aerosol is observed after major volcanic eruptions near
the Equator. The most significant eruption in recent times was Mount
Pinatubo in the Philippines (1991), which reduced the average global
temperature by ~0.5 K for ~2 years6, 7, 8, 9. As a result, research on the
deliberate injection of stratospheric aerosol has consequently focused on
the introduction of sulphate aerosol or precursor gases (SO2, H2S and OCS)
so as to mimic the volcanic effect10, 11, 12. Aerosol compositions other
than sulphate have been suggested, because they can offer more-effective
radiation scattering by virtue of having greater refractive
indices13, 14, 15, or possibly increase the particle lifetime in the
stratosphere by the use of photophoretic levitation16. Furthermore, if a
material with lower solar-radiation absorption is used, modelling suggests
significant reduction in stratospheric heating leading to a lower
perturbation of stratospheric circulation17.The most efficient use of
injected particles is achieved when particles are injected into the
tropical stratosphere (~20 km; Fig. 1). This injection strategy would
maximize their meridional distribution within the atmosphere and
atmospheric lifetime, owing to slow overturning (Brewer–Dobson) circulation
in the stratosphere as indicated in Fig. 1 (Refs 18,19). Optimized particle
properties could also minimize the amount of injected geoengineered
material required, and hence reduce the deposition flux of aerosol at
Earth's surface. Various methods for the introduction of geoengineered
particles into the stratosphere have been proposed20, 21, 22 and the choice
of delivery mechanism is beyond the scope of this Perspective.

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