http://m.iopscience.iop.org/1748-9326/8/1/014009

Environmental Research Letters Volume 8Number 1
Peter Köhler et al 2013 Environ. Res. Lett. 8014009
doi:10.1088/1748-9326/8/1/014009

Geoengineering impact of open ocean dissolution of olivine on atmospheric
CO2, surface ocean pH and marine biology

OPEN ACCESS

Peter Köhler, Jesse F Abrams1, Christoph Völker, Judith Hauck and Dieter A
Wolf-Gladrow

Abstract

Ongoing global warming induced by anthropogenic emissions has opened the
debate as to whether geoengineering is a 'quick fix' option. Here we
analyse the intended and unintended effects of one specific geoengineering
approach, which is enhanced weathering via the open ocean dissolution of
the silicate-containing mineral olivine. This approach would not only
reduce atmospheric CO2 and oppose surface ocean acidification, but would
also impact on marine biology. If dissolved in the surface ocean, olivine
sequesters 0.28 g carbon per g of olivine dissolved, similar to land-based
enhanced weathering. Silicic acid input, a byproduct of the olivine
dissolution, alters marine biology because silicate is in certain areas the
limiting nutrient for diatoms. As a consequence, our model predicts a shift
in phytoplankton species composition towards diatoms, altering the
biological carbon pumps. Enhanced olivine dissolution, both on land and in
the ocean, therefore needs to be considered as ocean fertilization. From
dissolution kinetics we calculate that only olivine particles with a grain
size of the order of 1 μm sink slowly enough to enable a nearly complete
dissolution. The energy consumption for grinding to this small size might
reduce the carbon sequestration efficiency by ~30%.

Dates
Issue 1 (March 2013)
Received 22 October 2012,
accepted for publication 7 January 2013
Published 21 January 2013

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