Hi list and bccs

Thankfully additional information on SRM interaction with atmospheric
anomalies was provided to me by a member, who chose to remain anonymous.
It's pasted verbatim below my signature.

Interestingly, in the course of compiling this, I've tried to discover the
origin of water in the Stratosphere. People seem to disagree on whether
methane or the troposphere is the larger source, but the best explanation I
had suggested that the ratio is probably fairly even, but varies quite a
lot.

I'd be interested to hear feedback on these issues.

A

--------

Large meteorite airbusts (eg Tunguska) Search Toon OB. Almost certainly
produced a lot of NOx, since shockwave would have been >Mach 6

Northern lights Probably way too high to do much to the stratosphere,
except maybe at centre of winter polar vortex. Big effects in mesosphere.

Solar storms / coronal mass ejection impact See previous answer.

Tropopause folding events Very important, much work done in last 50 years.
E F Danielsen, J Atmos Sci (1968) is seminal and instructive. See also WMO
Global Research and Ozone Monitoring Report No. 16, Chapter 5 (1986). Much
recent work by NCAR and Mainz groups in J Geophys Res – Atmospheres and in
Atmos Chem Phys.

The OH hole over the pacific Need a lot more observations to confirm the
reality.

Super-large wildfires (which apparently have plumes which affect the
stratosphere) Search pyrocumulus and SAGE 3 for satellite data and
CRYSTAL-FACE 2004 for aircraft data, authors E Ray + K H Rosenlof + EC
Richard especially.

Nuclear detonations P Goldsmith et al., Nature 244, 545-551 (1973),
“Nitrogen oxides, nuclear weapon testing, Concorde and stratospheric ozone”
is a good place to start. The history can be traced through the papers that
cite it, right up to last month by some Russians, who have a long history
in this field.

Space rocket exhaust Ross, MN et al., 2000, Observation of stratospheric
ozone depletion associated with Delta II rocket emissions, Geophys Res Lett
27, 2209-2212.

Here's some feedback on other stuff that's not strictly anomalies, as I
meant it, but is still good content :

> 1) What's not on your list yet is the tendency of increased stratospheric
carbon dioxide to provide a positive feedback effect on ozone, especially
in the upper stratosphere, via the negative temperature dependence of the
O+O2+M->O3+M reaction that is the sole source of stratospheric ozone. Known
about since Groves, Mattingly & Tuck, Nature, 273, 711-715 [1978] and 280,
127-129 [1979] and elaborated upon by GCM modellers from the 1990s onwards.
>
> 2) The uncertainties surrounding the chemical composition and physical
structure of aerosols are great, and given the nonlinear interactions
between radiation, composition and dynamics that has to be the main
concern. We simply don't have adequate predictive capability at present.

Another thing that's missing is nitrous oxide from agriculture. First
raised by M B McElroy in the 1970s, most recently modelled by A R
Ravishankara et al.

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