http://m.phys.org/_news335083927.html

Research spawns eco-friendly cement substitute

Nov 13, 2014 by Paul TumarkinDavid Stone's Ferrock "represents an amazing
engineering achievement that has the potential to create a great, positive
impact on the environment,” says Doug Hockstad of Tech Launch Arizona.

When he was a Ph.D. student in the University of Arizona Department of
Soil, Water, and Environmental Science, David Stone won a student
innovation competition with the invention of an eco-friendly substitute for
Portland cement.

The U.S. Patent and Trademark Office issued a patent for the UA invention
in 2013, and today, in collaboration with Tech Launch Arizona, Stone has
licensed the technology from the UA and is starting a company called Iron
Shell to commercialize his invention.The invention, called Ferrock, uses
the waste steel dust from industrial processes to create a cement-like
material that is sustainable, strong and environmentally superior to
conventional cement. Cement is the binder in concrete, which also includes
aggregate such as sand and gravel.

Along with turning a waste product that usually ends up in landfills into a
useful product, Ferrock has another —perhaps even greater—environmental
advantage. Annually, 4 billion metric tons of cement is made worldwide for
use in concrete, and for every ton of cement manufactured, approximately
one ton of carbon dioxide is released into the atmosphere.

Conversely, Ferrock hardens only when exposed to high concentrations of
carbon dioxide, which is absorbed and trapped, making it a carbon negative
material. This greenhouse gas diffuses into the wet mixture and reacts with
the iron, creating iron carbonate and becoming part of the material's
mineral matrix.

Lab testing shows that Ferrock is significantly stronger than Portland
cement in compressive strength and several times stronger in flexural
strength, meaning it can take more stress before bending and breaking. It
also has superior resistance to cracking. Because hardening is caused by
the rusting of iron dust, it is well-suited for use in salt water and other
environments that are too corrosive for regular cement."

This all started from an accidental discovery in a lab, which is actually
the way it usually goes," Stone says. "That was back in 2002, and I
included as much as I knew in my doctoral dissertation. But the work goes
on. It has taken years to get just a basic understanding of the chemistry
involved. But this shouldn't be surprising, since scientists are still
trying to figure out Portland cement and they've had 200 years.

"I am into this for the long haul. Time is on our side, since in this era
of global warming unsustainable processes like cement manufacture will have
to give way to greener alternatives."Doug Hockstad, Tech Launch Arizona's
director of tech transfer, is excited by the prospects for Iron Shell.

"The technology stands to impact the world in a variety of ways," Hockstad
says, "including both reduction of carbon dioxide production and
sequestration of other carbon dioxide production, as well as recycling of
waste products such as steel waste and in some cases, recycled glass. For
all that, this represents an amazing engineering achievement that has the
potential to create a great, positive impact on the environment."

Stone says TLA's role has been substantial."Scientist inventors are not
exactly known for their business skills, but (TLA) believed in me from the
beginning and felt that I should play a central role in the
commercialization effort," he says. "They then demonstrated this belief by
giving my own startup the exclusive license to the patent and the right to
sublicense. The terms were very generous and demonstrated that they think
this commercialization effort will succeed. Beyond that, they have
continuously aided my efforts to find business advisors, get the expertise
I need and build a team."

Provided by University of Arizona

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