http://www.reportingclimatescience.com/news-stories/article/study-casts-doubt-on-iron-seeded-ocean-carbon-storage.html

>From the Alfred Wegener Institute

A new study performed by a team of international scientists reveals that a
complex ecosystem response to iron fertilization in the Southern Ocean
might reduce the efficiency of biological carbon pump in transporting
carbon dioxide into the deep ocean.

Lead author Dr. Ian Salter from the Alfred Wegener Institute, Helmholtz
Centre for Polar and Marine Research (AWI) in Bremerhave, Germany, and a
team of international collaborators, discovered that iron fertilization
significantly promotes the growth of shelled organisms that feed on
phytoplankton. These organisms produce carbon dioxide when building their
calcareous shells.

In a naturally iron-fertilized system in the Southern Ocean the growth and
sinking of these shelled grazers reduces deep-ocean storage of carbon
dioxide by up to 30 per cent. Ignoring the response of these organisms
could result in an overestimate of the marine carbon dioxide storage
capacity resulting from ocean iron fertilization, a potential strategy for
the mitigation of climate change. The study is published by the scientific
journal Nature Geoscience.

The Southern Ocean plays an important role in the exchange of carbon
dioxide between the atmosphere and the ocean. One aspect of this is the
growth of phytoplankton, which acts as a natural sponge for carbon dioxide,
drawing the troublesome greenhouse gas from the atmosphere into the sea.
When these plankton die they can sink to the bottom of the ocean and store
some of the carbon dioxide they have absorbed, a process scientists call
the “biological carbon pump”

.Although many areas of the Southern Ocean are rich in nutrients, they
often lack iron, which limits phytoplankton growth. An important idea in
oceanography is that adding iron to the Southern Ocean could stimulate
phytoplankton growth and the biological carbon pump. Some scientists
believe that this process can partly explain cycles in atmospheric carbon
dioxide over Earth’s recent history and it has also been widely debated as
a mitigation strategy for climate change.In two previous studies carried
out in the last five years it has been shown that iron fertilization of the
Southern Ocean can export carbon dioxide to the deep-sea. “However, to
understand the net storage of carbon dioxide in the ocean interior, sinking
phytoplankton are only one part of the story”, explains Dr. Ian Salter from
the Alfred Wegener Institute. “These phytoplankton can be a food source for
certain types of planktonic grazers, foraminifer and pteropods, that make
shells from calcium carbonate - a process which produces carbon dioxide”.

The biogeochemist, and an international team of collaborators, were the
first to quantify production and sinking of these calcium carbonate shells
resulting from a phytoplankton bloom in the Southern Ocean, close to the
Crozet Islands, with surprising results. Natural fertilization, caused by
iron leached from the basaltic islands, increased the production and
sinking of these calcium carbonate shells to a greater extent than sinking
phytoplankton. This has important implications for the deep-sea storage of
the carbon dioxide resulting from these blooms.

“The production and sinking of these calcium carbonate shells affects the
balance of carbon dioxide in the surface ocean over 100 to 1000 year
timescales”, explains Dr. Ian Salter. “Our calculations suggest that this
process reduces the amount of carbon dioxide transferred to the ocean
interior via sinking phytoplankton by up to 30 per cent in this naturally
fertilized system. However, it is unclear that purposefully added iron
would have the same impact.”Interestingly the reduction in the efficiency
of the biological carbon pump was not just caused by a higher abundance of
these organisms, but also by changes in species composition. “In our
samples from iron fertilized areas we found more species that produce
larger calcium carbonate shells, and in turn produce more carbon dioxide
per individual”, explains the biogeochemist. Iron fertilization can
therefore affect biodiversity and ecosystem structure with important
knock-on effects for climate interactions. “It is important to recognise
that our findings are only from a specific area of the Southern Ocean. The
ecology of these shelled organisms can be very different depending on the
species and exactly where in the ocean they live”, cautions Dr. Ian Salter.

In future research projects Dr. Ian Salter will continue to investigate the
sinking of phytoplankton and shelled calcifying organisms in other
naturally iron-fertilized areas of the Southern Ocean, in addition to the
Arctic Ocean, where melting sea ice conditions may also affect this
delicate balance.

The production of organic carbon in the ocean’s surface and its subsequent
downward export transfers carbon dioxide to the deep ocean. This
CO2 drawdown is countered by the biological precipitation of carbonate,
followed by sinking of particulate inorganic carbon, which is a source of
carbon dioxide to the surface ocean, and hence the atmosphere over
100–1,000 year timescales. The net transfer of CO2 to the deep ocean is
therefore dependent on the relative amount of organic and inorganic carbon
in sinking particles. In the Southern Ocean, iron fertilization has been
shown to increase the export of organic carbon3–5, but it is unclear to
what degree this effect is compensated by the export of inorganic carbon.
Here we assess the composition of sinking particles collected from sediment
traps located in the Polar Frontal Zone of the Southern Ocean. We find that
in high-nutrient, low-chlorophyll regions that are characterized by
naturally high iron concentrations, fluxes of both organic and inorganic
carbon are higher than in regions with no iron fertilization. However, the
excess flux of inorganic carbon is greater than that of organic carbon. We
estimate that the production and flux of carbonate in naturally
iron-fertilized waters reduces the overall amount of CO2 transferred to the
deep ocean by 6–32%, compared to 1–4% at the non-fertilized site. We
suggest that an increased export of organic carbon, stimulated by iron
availability in the glacial sub-Antarctic oceans, may have been accompanied
by a strengthened carbonate counter pump.

Carbonate counter pump stimulated by natural iron fertilization in the
Polar Frontal Zone by Ian Salter, Ralf Schiebel, Patrizia Ziveri, Aurore
Movellan, Richard Lampitt and George A.Wolff published in Nature
Geoscience, 10 November 2014 DOI: 10.1038/NGEO2285

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