Poster's note : paper link below with abstract. NB plain English article
previously posted on list -
http://www.the-scientist.com/?articles.view/articleNo/41564/title/Complexities-of-Carbon-Lowering/
<http://www.nature.com/ngeo/journal/v7/n12/full/ngeo2285.html>

http://www.nature.com/ngeo/journal/v7/n12/full/ngeo2285.html

Carbonate counter pump stimulated by natural iron fertilization in the
Polar Frontal Zone

Ian Salter, Ralf Schiebel, Patrizia Ziveri, Aurore Movellan, Richard
Lampitt & George A. Wolff

Nature Geoscience 7, 885–889 (2014)
doi:10.1038/ngeo2285
Published online 10 November 2014

The production of organic carbon in the ocean’s surface and its subsequent
downward export transfers carbon dioxide to the deep ocean. This CO2
drawdown is countered by the biological precipitation of carbonate,
followed by sinking of particulate inorganic carbon, which is a source of
carbon dioxide to the surface ocean, and hence the atmosphere over
100–1,000 year timescales. The net transfer of CO2 to the deep ocean is
therefore dependent on the relative amount of organic and inorganic carbon
in sinking particles. In the Southern Ocean, iron fertilization has been
shown to increase the export of organic carbon, but it is unclear to what
degree this effect is compensated by the export of inorganic carbon. Here
we assess the composition of sinking particles collected from sediment
traps located in the Polar Frontal Zone of the Southern Ocean. We find that
in high-nutrient, low-chlorophyll regions that are characterized by
naturally high iron concentrations, fluxes of both organic and inorganic
carbon are higher than in regions with no iron fertilization. However, the
excess flux of inorganic carbon is greater than that of organic carbon. We
estimate that the production and flux of carbonate in naturally
iron-fertilized waters reduces the overall amount of CO2 transferred to the
deep ocean by 6–32%, compared to 1–4% at the non-fertilized site. We
suggest that an increased export of organic carbon, stimulated by iron
availability in the glacial sub-Antarctic oceans, may have been accompanied
by a strengthened carbonate counter pump.

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