Hi Mike,

The figure is useful:  If 597 (atm) had been in equilibrium with 900 (mixed 
layer) pre-industrial, how can 597+165 be within a few Gt(C) of equilibrium 
with 900 + 18? If the atm. and the mixed layer of the sea are that far out of 
equilibrium, seems to me the sink will operate for a while (decades) even if 
future emissions =   current sink over that period.  In other words, what I am 
questioning is whether there would, within a year, be a hugely reduced 
gradient.  Am I misinterpreting the numbers in the figure???

It will be nice to sort this out!!

John


John Harte
Professor of Ecosystem Sciences
ERG/ESPM
310 Barrows Hall
University of California
Berkeley, CA 94720  USA
[email protected]



On Jan 25, 2015, at 6:16 PM, Mike MacCracken <[email protected]> wrote:

> Hi John—So I have attached a diagram of the carbon cycle from IPCC AR4WG1 
> Figure 7.3 that shows natural flows (in black) and then the augmentations as 
> a result of human activities (in red) 
> 
> There is a time constant for uptake of particular molecules of CO2 into the 
> mixed layer, so mass in mixed layer divided by atmospheric flux, and that is 
> 10 years (what I think you are referring to).  I don’t think, however, that 
> this is what determines the lag time for the net flux and so what counts in 
> what we have been talking about—basically, if there were suddenly no 
> gradient, there would immediately be no net flux and it does not matter which 
> molecule is where. So, in my view, what matters is the gradient that is 
> created by each year’s emissions, and as that goes down, the gradient will be 
> less, and if the atmospheric concentration were suddenly held stable, the 
> driving gradient would pretty quickly go to zero (there would still be the 
> gradient with the deep ocean as its cycle time is of order 1000 years, so the 
> flux to the deep ocean would continue.
> 
> And I don’t think there is anywhere near a 10-year lag in the concentration 
> gradient between the atmosphere and the concentration at the top of the mixed 
> layer—nor do I think that the vertical mixing time down of order 100-200 
> meters in the upper ocean layer is anything like a decade given wave and 
> isopychnal mixing and wind driven flows—I’d suggest less than a year, but 
> that is a guess. [WE NEED AN AUTHORITATIVE COMMENT FROM KEN C].
> 
> Best, Mike
> 
> 
> 
> 
> On 1/25/15, 6:10 PM, "John Harte" <[email protected]> wrote:
> 
>> Mike, I could be wrong but i was under the impression that the relevant time 
>> constant (inverse rate const.)  characterizing the gradient-driven gross 
>> flow of CO2 from air to sea is on the order of a decade or two.  A result I 
>> thought obtained from C14 tracer studies.  I am also under the impression 
>> that the year to year variation in the sink strength does not track annual 
>> emissions very closely, suggesting that there are longer time constants in 
>> the system (as well as "noise" from variations in wind etc. and inter annual 
>> variability in the terrestrial sink).  
>> 
>> It's been a while since I looked at this so maybe my understanding is out of 
>> date.  
>> 
>> 
>> Cheers,
>> 
>> John
>>  
>> John Harte
>> Professor of Ecosystem Sciences
>> ERG/ESPM
>> 310 Barrows Hall
>> University of California
>> Berkeley, CA 94720  USA
>> [email protected]
>> 
>> 
>> 
>> On Jan 25, 2015, at 1:27 PM, Mike MacCracken <[email protected]> wrote:
>> 
>>> Re: [geo] Energy Planning and Decarbonization Technology | The Energy 
>>> Collective 
>>> Hi John and Greg—So responding to both messages (and I pasted John’s into 
>>> the thread)
>>> 
>>> I would think the terrestrial biosphere time constant is a decade or two, 
>>> but for the ocean, I’d suggest that it is much shorter. My understanding is 
>>> that the time constant of the wind-stirred ocean mixed layer is a year or 
>>> two—not a decade or two. Changing the net flux rate to the deep ocean would 
>>> be pretty slow, but that net flux is pretty small.
>>> 
>>> And so, how would it work. Well, in terms of the net flux to the ocean, the 
>>> CO2 is driven into the upper ocean by the gradient between the atmosphere 
>>> and the upper ocean, so once one stabilizes the atmospheric concentration 
>>> and the ocean mixed layer concentration catches, up, there will be no 
>>> gradient to drive the flux. 
>>> 
>>> Well, this is not quite correct as the net flux to the deep ocean would 
>>> continue, so there could be a net flux from the atmosphere to the upper 
>>> ocean to make up that difference. However, the ocean surface layer would 
>>> also continue to warm as there is a lag in the thermal term—and so the 
>>> warmer the mixed layer, the higher the CO2 partial pressure would be and 
>>> this would tend to resist uptake of CO2.
>>> 
>>> In terms of gross fluxes, the carbon rich upwelling waters would end up 
>>> giving off a bit more CO2 with CO2 stabilization as opposed to the 
>>> situation were the CO2 higher, and the uptake in high latitudes where water 
>>> is cold would not be going up because the atmosphere-upper ocean gradient 
>>> would be less, so again, one would lose the ocean sink, and that would mean 
>>> that a greater share of any emissions that did occur (so in reducing the 
>>> CO2 emissions from 37 Gt CO2/yr, one does not get to assume the ocean sink 
>>> would continue as it has—and I suspect that would be a pretty fast 
>>> adjustment.
>>> 
>>> For the biosphere, John suggests that he is quite concerned about the 
>>> continuance of the terrestrial sink (basically, it seems, whether or not 
>>> one stabilizes the CO2 concentration).
>>> 
>>> So, as I indicated initially, it seems to me that one would pretty quickly 
>>> need to be taking up 90% of the 37 GtCO2/yr by your proposed approach—and 
>>> that is a lot of carbon to be taking up. Hence, I’ll stand by my earlier 
>>> statement that it will be hard for CDR/atmospheric and oceanic scrubbing to 
>>> make much of a difference with respect to slowing the rate of climate 
>>> change until emissions drop a lot.
>>> 
>>> Mike
>>> 
>>> 
>>> Msg from John Harte—combined into this thread.
>>> 
>>> Mike, I think the truth is flanked by your's and Greg's statements.  If we 
>>> were to reduce emissions starting immediately so that each year from here 
>>> on out we emit only about half current emissions, then for a decade or two, 
>>> at least, the current carbon sink would roughly equal emissions and the CO2 
>>> level would be roughly constant, as Greg suggests. The concentration 
>>> gradient between air and sea would slowly shrink however and so in the 
>>> longer run the sink strength would diminish and emissions would have to be 
>>> reduced further.  At a steady annual flow from air to sea of 15 - 20 
>>> Gt(CO2)/y, however, it would take decades before there was an appreciable 
>>> diminishment of that sink flow.  The real shorter-term danger I think is 
>>> that soil warming and forest dieback leading to terrestrial sources of CO2, 
>>> along with possible CH4 releases, all because of the warming associated 
>>> with trying to keep a steady 400 ppm of CO2, would necessitate much greater 
>>> emissions reduction and the sooner we achieve that the better.  
>>> 
>>> John Harte
>>> Professor of Ecosystem Sciences
>>> ERG/ESPM
>>> 310 Barrows Hall
>>> University of California
>>> Berkeley, CA 94720  USA
>>> [email protected] <x-msg://4873/[email protected]> 
>>> 
>>> 
>>> On 1/25/15, 3:23 PM, "Greg Rau" <[email protected] 
>>> <x-msg://4873/[email protected]> > wrote:
>>> 
>>>> I'm not necessarily advocating lowering air pCO2, but stabilizing pCO2 say 
>>>> at the present 400 uatms. If this is stable, how does additional ocean 
>>>> degassing ensue? Exactly how much CDR would be needed to achieve this, the 
>>>> resulting response of natural CDR and natural emissions, and the required 
>>>> time course of this I will leave to the modelers. Ditto for achieving 
>>>> stability via pure anthro emissions reduction. Obviously, some combination 
>>>> of these will, in my opinion, be needed to stabilize pCO2.  Anthro 
>>>> emissions reduction would appear to have significant technological and 
>>>> policy awareness lead relative to CDR. I'm suggesting this needs to 
>>>> change, in case emissions reduction alone continues to fail to achieve its 
>>>> promise. 
>>>> 
>>>> As for reducing air pCO2, this already happens on an intra-annual basis 
>>>> thanks to natural CDR and in spite of ocean degassing: 
>>>> https://scripps.ucsd.edu/programs/keelingcurve/2013/10/23/the-annual-rise-in-co2-levels-has-begun/#more-940
>>>>   Is it unthinkable that this decline  couldn't be increased to some 
>>>> degree via human intervention? Wouldn't it be desirable/necessary to 
>>>> investigate this in the now likely event that current policies and actions 
>>>> have us blowing by the pCO2 "safety threshold" for decades if not 
>>>> centuries, or beyond if permafrost/clathrate degassing ensues?
>>>> Greg
>>>> 
>>>>>  
>>>>>  
>>>>>  
>>>>>  
>>>>>   From: Mike MacCracken <[email protected] 
>>>>> <x-msg://4873/[email protected]> >
>>>>>  To: Greg Rau <[email protected] <x-msg://4873/[email protected]> >; 
>>>>> Geoengineering <[email protected] 
>>>>> <x-msg://4873/[email protected]> > 
>>>>>  Sent: Sunday, January 25, 2015 11:10 AM
>>>>>  Subject: Re: [geo] Energy Planning and Decarbonization Technology | The 
>>>>> Energy Collective
>>>>>   
>>>>>  
>>>>> 
>>>>> Re: [geo] Energy Planning and Decarbonization Technology | The Energy 
>>>>> Collective
>>>>> Hi Greg--The problem with your calculation is that if you were to take 
>>>>> CO2 out of the atmosphere, the ocean and biosphere would readjust to the 
>>>>> lower atmospheric concentration and return to the atmosphere that they 
>>>>> have taken up earlier when the original amount of CO2 was emitted. Thus, 
>>>>> you really have to figure out how to sequester 90+% of the 37 Gt CO2/yr 
>>>>> that is emitted—you don’t get to keep counting the 20 Gt CO2 taken up by 
>>>>> the ocean and the biosphere.
>>>>> 
>>>>> Mike 
>>>>> 
>>>>> 
>>>>> On 1/25/15, 1:25 PM, "Greg Rau" <[email protected] 
>>>>> <x-msg://4873/[email protected]> > wrote:
>>>>> 
>>>>>> Just to be clear, we currently emit 37.0 GT CO2/yr, yet in the short 
>>>>>> term only 17.5 Gt/yr remain in the atmosphere, the rest being removed by 
>>>>>> natural CDR (reviewed here: 
>>>>>> http://www.nature.com/nclimate/journal/v4/n10/full/nclimate2392.html ). 
>>>>>> So our net emissions is 17.5 Gt/yr.  Cutting this by 90% via enhanced 
>>>>>> CDR alone would mean removing an additional 15.8 GT CO2/yr over and 
>>>>>> above the 19.5 Gt/yr already removed, a 81% increase in CDR. Is this 
>>>>>> sufficient to stabilize air pCO2 or lower pCO2?  If the latter then we'd 
>>>>>> also have to contend with legacy CO2 degassing from the ocean. It should 
>>>>>> be easier to reduce emissions than increase CDR, but then how is that 
>>>>>> going?  I'd say it's time to find out just how easy or hard additional 
>>>>>> CDR is, relative to the technical, economic and political difficulties 
>>>>>> of emissions reduction, and relative to the consequences if the latter 
>>>>>> strategy continues to seriously underperform.
>>>>>> Greg
>>>>>> 
>>>>>>>  
>>>>>>>  
>>>>>>>  
>>>>>>>  
>>>>>>>   From: Mike MacCracken <[email protected] 
>>>>>>> <x-msg://4873/[email protected]> >
>>>>>>>  To: Greg Rau <[email protected] <x-msg://4873/[email protected]> 
>>>>>>> >; Geoengineering <[email protected] 
>>>>>>> <x-msg://4873/[email protected]> > 
>>>>>>>  Sent: Sunday, January 25, 2015 8:27 AM
>>>>>>>  Subject: Re: [geo] Energy Planning and Decarbonization Technology | 
>>>>>>> The Energy Collective
>>>>>>>   
>>>>>>>  
>>>>>>> 
>>>>>> Re: [geo] Energy Planning and Decarbonization Technology | The Energy 
>>>>>> Collective
>>>>>> Let me expand my quick description to be 90% cut in human-induced 
>>>>>> emissions (on top of all the natural sinks), so natural CDR does not 
>>>>>> count.
>>>>>> 
>>>>>> And on the proposed removal industry, for $100 per ton of CO2, an awful 
>>>>>> lot could be done to replace fossil fuels with other sources of energy, 
>>>>>> or even better efficiency, a huge amount of which could be done for much 
>>>>>> less, if we’d try. So, nice that there is a CO2 removal approach as a 
>>>>>> backstop to what the cost of changing energy would be—basically, you are 
>>>>>> suggesting it should cost less than $100 per ton of CO2 to address the 
>>>>>> problem. With the new paper in Nature (lead author is a former intern 
>>>>>> that worked with me at the Climate Institute) that the social cost of 
>>>>>> CO2 is more than twice the cost of, then it makes huge economic sense to 
>>>>>> be addressing the problem. So, indeed, let’s get on with it—research 
>>>>>> plus actually dealing with the issue.
>>>>>> 
>>>>>> Mike
>>>>>> 
>>>>>> 
>>>>>> 
>>>>>> 
>>>>>> On 1/24/15, 1:40 PM, "Greg Rau" <[email protected] 
>>>>>> <x-msg://4873/[email protected]> > wrote:
>>>>>> 
>>>>>>> Mike,
>>>>>>> If it takes "a 90% cut in CO2 to stop the rise in atmospheric 
>>>>>>> concentration", we are already more than half way there thanks to 
>>>>>>> natural CDR. About 55% of our CO2 emissions are mercifully removed from 
>>>>>>> air via biotic and abiotic processes. So just 35% to go?  
>>>>>>> As for "CDR replacing the fossil fuel industry", here's one way to do 
>>>>>>> that: http://www.pnas.org/content/110/25/10095.full  , but low fossil 
>>>>>>> energy prices (or lack of sufficient C emissions surcharge) are 
>>>>>>> unlikely to make this happen. Certainly agree that we need all hands 
>>>>>>> and ideas on deck in order to stabilize air CO2. But for reasons that 
>>>>>>> continue to baffle me, that is not happening at the policy, decision 
>>>>>>> making, and R&D levels it needs to.  
>>>>>>> Greg
>>>>>>> 
>>>>>>>>  
>>>>>>>>  
>>>>>>>>  
>>>>>>>>  
>>>>>>>>   From: Mike MacCracken <[email protected] 
>>>>>>>> <x-msg://4873/[email protected]> >
>>>>>>>>  To: Geoengineering <[email protected] 
>>>>>>>> <x-msg://4873/[email protected]> > 
>>>>>>>>  Sent: Saturday, January 24, 2015 9:06 AM
>>>>>>>>  Subject: Re: [geo] Energy Planning and Decarbonization Technology | 
>>>>>>>> The Energy Collective
>>>>>>>>   
>>>>>>>>  
>>>>>>>> 
>>>>>>>> Re: [geo] Energy Planning and Decarbonization Technology | The Energy 
>>>>>>>> Collective
>>>>>>>> In terms of an overall strategy, it takes of order a 90% cut in CO2 
>>>>>>>> emissions to stop the rise in the atmospheric concentration, and that 
>>>>>>>> has to happen to ultimately stabilize the climate (and it would be 
>>>>>>>> better to have the CO2 concentration headed down so we don’t get to 
>>>>>>>> the equilibrium warming for the peak concentration we reach (recalling 
>>>>>>>> we will be losing sulfate cooling).
>>>>>>>> 
>>>>>>>> Thus, to really stop the warming, CDR in its many forms has to be at 
>>>>>>>> least as large as 90% of CO2 emissions (from fossil fuels and 
>>>>>>>> biospheric losses). That is a lot of carbon to be taking out of the 
>>>>>>>> system by putting olivine into the ocean, biochar, etc. at current 
>>>>>>>> global emissions levels (that are still growing). The greater the 
>>>>>>>> mitigation (reduction in fossil fuel emissions), the more effective 
>>>>>>>> CDR can be—what would really be nice is CDR replacing the fossil fuel 
>>>>>>>> industry so ultimately it is as large. I’d suggest this is why it is 
>>>>>>>> really important to always be mentioning the importance of all the 
>>>>>>>> other ways, in addition to CDR, to be cutting emissions—that is really 
>>>>>>>> critical.
>>>>>>>> 
>>>>>>>> Mike
>>>>>>>> 
>>>>>>>> 
>>>>>>>> On 1/24/15, 10:19 AM, "Stephen Salter" <[email protected] 
>>>>>>>> <x-msg://4873/[email protected]> > wrote:
>>>>>>>> 
>   
> Hi All
>  
>  Paragraph 2 mentions 'carbon negative' nuclear energy.  The carbon emissions 
> from a complete, working nuclear power station are mainly people driving to 
> work.  But digging, crushing and processing uranium ore needs energy and 
> releases carbon in inverse proportion to the ore grade.  There were some 
> amazingly high grade ores, some once even at the critical point for reaction, 
> but these have been used.  Analysis by van Leeuwen concludes that the carbon 
> advantage of present nuclear technology over gas is about three but that the 
> break-even point comes when the ore grade drops to around 100 ppm.  This 
> could happen within the life of plant planned now.
>  
>  As we do not know how to do waste disposal we cannot estimate its carbon 
> emissions.  But just because we cannot calculate them does not mean that they 
> are zero.
>  
>  Stephen 
>  
>  
>   
> Emeritus Professor of Engineering Design. School of Engineering. University 
> of Edinburgh. Mayfield Road. Edinburgh EH9 3JL. Scotland [email protected] 
> <x-msg://4873/[email protected]>  Tel +44 (0)131 650 5704 Cell 07795 203 195 
> WWW.see.ed.ac.uk/~shs <http://WWW.see.ed.ac.uk/~shs>  
> <http://WWW.see.ed.ac.uk/~shs>  YouTube Jamie Taylor Power for Change
>  
>  On 24/01/2015 14:56, Andrew Lockley wrote:
>  
>  
>  
> 
> Poster's note : none of this explains why there's any need for integration. 
> Chucking olivine in the sea seems easier and cheaper than all. 
>  
> 
> http://theenergycollective.com/noahdeich/2183871/3-ways-carbon-removal-can-help-unlock-promise-all-above-energy-strategy
>  
> 
> 3 Ways Carbon Removal can Help Unlock the Promise of an All-of-the-Above 
> Energy Strategy
>  
> 
> January 24, 2015
>  
>  
> 
> “We can’t have an energy strategy for the last century that traps us in the 
> past. We need an energy strategy for the future – an all-of-the-above 
> strategy for the 21st century that develops every source of American-made 
> energy.”– President Barack Obama, March 15, 2012
>  
> 
> An all-of-the-above energy strategy holds great potential to make our energy 
> system more secure, inexpensive, and environmentally-friendly. Today’s 
> approach to all-of-the-above, however, is missing a key piece: carbon dioxide 
> removal (“CDR”). Here’s three reasons why CDR is critical for the success of 
> an all-of-the-above energy strategy:
>  
> 
> 1. CDR helps unite renewable energy and fossil fuel proponents to advance 
> carbon capture and storage (“CCS”) projects. Many renewable energy advocates 
> view CCS as an expensive excuse to enable business-as-usual fossil fuel 
> emissions. But biomass energy with CCS (bio-CCS) projects are essentially 
> “renewable CCS” (previously viewed as an oxymoron), and could be critical for 
> drawing down atmospheric carbon levels in the future. As a result, fossil CCS 
> projects could provide a pathway to “renewable CCS” projects in the future. 
> Because of the similarities in the carbon capture technology for fossil and 
> bioenergy power plants, installing capture technology on fossil power plants 
> today could help reduce technology and regulatory risk for bio-CCS projects 
> in the future. What’s more, bio-CCS projects can share the infrastructure for 
> transporting and storing CO2 with fossil CCS installations. Creating such a 
> pathway to bio-CCS should be feasible through regulations that increase 
> carbon prices and/or biomass co-firing mandates slowly over time, and could 
> help unite renewable energy and CCS proponents to develop policies that 
> enable the development of cost-effective CCS technology.
>  
> 
> 2. CDR bolsters the environmental case for nuclear power by enabling it to be 
> carbon “negative”: Many environmental advocates say that low-carbon benefits 
> of nuclear power are outweighed by the other environmental and safety 
> concerns of nuclear projects. The development of advanced nuclear projects 
> paired with direct air capture (“DAC”) devices, however, could tip the scales 
> in nuclear’s favor. DAC systems that utilize the heat produced from nuclear 
> power plants can benefit from this “free” source of energy to potentially 
> sequester CO2 directly from the atmosphere cost-effectively. The ability for 
> nuclear + DAC to provide competitively-priced, carbon-negative energy could 
> help convince nuclear power’s skeptics to support further investigation into 
> developing safe and environmentally-friendly advanced nuclear systems.
>  
> 
> 3. CDR helps enable a cost-effective transition to a decarbonized economy: 
> Today, environmental advocates claim that prolonged use of fossil fuels is 
> mutually exclusive with preventing climate change, and fossil fuel advocates 
> bash renewables as not ready for “prime time” — i.e. unable to deliver the 
> economic/development benefits of inexpensive fossil energy. To resolve this 
> logjam, indirect methods of decarbonization — such as a portfolio of low-cost 
> CDR solutions — could enable fossil companies both to meet steep emission 
> reduction targets and provide low-cost fossil energy until direct 
> decarbonization through renewable energy systems become more cost-competitive 
> (especially in difficult to decarbonize areas such as long-haul trucking and 
> aviation).
>  
> 
> Of course, discussion about the potential for CDR to enable an 
> all-of-the-above energy strategy is moot unless we invest in developing a 
> portfolio of CDR approaches. But if we do make this investment in CDR, an 
> all-of-the-above energy strategy that delivers a diversified, low-cost, and 
> low-carbon energy system stands a greater chance of becoming a reality. 
>  
> 
> Noah Deich
>  
> 
> Noah Deich is a professional in the carbon removal field with six years of 
> clean energy and sustainability consulting experience. Noah currently works 
> part-time as a consultant for the Virgin Earth Challenge, is pursuing his MBA 
> from the Haas School of Business at UC Berkeley, and writes a blog dedicated 
> to carbon removal (carbonremoval.wordpress.com 
> <http://carbonremoval.wordpress.com>  <http://carbonremoval.wordpress.com 
> <http://carbonremoval.wordpress.com/>  <http://carbonremoval.wordpress.com/>  
> <http://carbonremoval.wordpress.com/>  <http://carbonremoval.wordpress.com/> 
> > )
> 
>    
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>  
>  
>  
>>>>> 
>>>>> 
>>>>>  
>>>>>  
>>>>>  
>>>>   
>>>> 
> <Anthropogenic_carbon_cycle.png>

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