Cleans up wastewater, removes CO2, generates H2, and produces beneficial ocean 
alkalinity.  What's not to like?
Greg

http://www.colorado.edu/news/releases/2015/08/03/cu-boulder-researchers-use-wastewater-treatment-capture-co2-emissions-and

http://pubs.acs.org/doi/full/10.1021/acs.est.5b00875

CU-Boulder researchers use wastewater treatment to capture CO2 emissions and 
produce energy

August 3, 2015
Cleaning up municipal and industrial wastewater can be dirty business, but 
engineers at the University of Colorado Boulder have developed an innovative 
wastewater treatment process that not only mitigates carbon dioxide (CO2) 
emissions, but actively captures greenhouse gases as well.

The treatment method, known as Microbial Electrolytic Carbon Capture (MECC), 
purifies wastewater in an environmentally-friendly fashion by using an 
electrochemical reaction that absorbs more CO2 than it releases while creating 
renewable energy in the process.

“This energy-positive, carbon-negative method could potentially contain huge 
benefits for a number of emission-heavy industries,” said Zhiyong Jason Ren, an 
associate professor of Civil, Environmental, and Architectural Engineering at 
CU-Boulder and senior author of the new study, which was recently published in 
the journal Environmental Science and Technology.

Wastewater treatment typically produces CO2 emissions in two ways: the fossil 
fuels burned to power the machinery, and the decomposition of organic material 
within the wastewater itself.  Plus, existing wastewater treatment technologies 
consume high amounts of energy. Public utilities in the United States treat an 
estimated 12 trillion gallons of municipal wastewater each year and consume 
approximately 3 percent of the nation’s grid energy.

Existing carbon capture technologies are energy-intensive and often entail 
costly transportation and storage procedures. MECC uses the natural 
conductivity of saline wastewater to facilitate an electrochemical reaction 
that is designed to absorb CO2 from both the water and the air.  The process 
transforms CO2 into stable mineral carbonates and bicarbonates that can be used 
as raw materials by the construction industry, used as a chemical buffer in the 
wastewater treatment cycle itself or used to counter acidity downstream from 
the process such as in the ocean.

The reaction also yields excess hydrogen gas, which can be stored and harnessed 
as energy in a fuel cell.

The findings offer the possibility that wastewater could be treated effectively 
on-site without the risks or costs typically associated with disposal.  Further 
research is needed to determine the optimal MECC system design and assess the 
potential for scalability.

“The results should be viewed as a proof-of-concept with promising implications 
for a wide range of industries,” said Ren.

Power companies have many reasons to perk up at the possibility of a 
carbon-negative wastewater treatment solution. The Environmental Protection 
Agency’s Clean Power Plan, expected to take full effect in the year 2020, will 
require power plants to comply with reduced CO2 emission levels.

The study may also have positive long-term implications for the world’s oceans. 
 Approximately 25 percent of CO2 emissions are subsequently absorbed by the 
sea, which lowers pH, alters ocean chemistry and hence threatens marine 
organisms, especially coral reefs and shellfish. Dissolved carbonates and 
bicarbonates produced via MECC, however, could act to chemically counter these 
effects if added to the ocean.

“This treatment system generates alkalinity through electrochemical means and 
we could potentially use that to help offset the effects of ocean 
acidification,” said Greg Rau, a senior researcher at the Institute of Marine 
Sciences at the University of California Santa Cruz and a co-author of the 
study. “This is one of several environmentally-friendly things this technology 
does.”

Many wastewater treatment plants are located on coastlines, raising the 
possibility that future MECC implementation in these facilities could couple 
both CO2 and ocean acidity mitigation.

Lu Lu and Zhe Huang, both graduate researchers in the Department of Civil, 
Environmental, and Architectural Engineering at CU-Boulder, co-authored the 
study. The National Science Foundation provided funding for the research.


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