http://iopscience.iop.org/article/10.1088/1748-9326/11/2/024007

Environmental Research Letters

Iron fertilisation and century-scale effects of open ocean dissolution of
olivine in a simulated CO2 removal experiment

Judith Hauck, Peter Köhler, Dieter Wolf-Gladrowand Christoph Völker

Published 9 February 2016
Environmental Research Letters, Volume 11,Number 2

Abstract

Carbon dioxide removal (CDR) approaches are efforts to reduce the
atmospheric CO2 concentration. Here we use a marine carbon cycle model to
investigate the effects of one CDR technique: the open ocean dissolution of
the iron-containing mineral olivine. We analyse the maximum CDR potential
of an annual dissolution of 3 Pg olivine during the 21st century and focus
on the role of the micro-nutrient iron for the biological carbon pump.
Distributing the products of olivine dissolution (bicarbonate, silicic
acid, iron) uniformly in the global surface ocean has a maximum CDR
potential of 0.57 gC/g-olivine mainly due to the alkalinisation of the
ocean, with a significant contribution from the fertilisation of
phytoplankton with silicic acid and iron. The part of the CDR caused by
ocean fertilisation is not permanent, while the CO2 sequestered by
alkalinisation would be stored in the ocean as long as alkalinity is not
removed from the system. For high CO2 emission scenarios the CDR potential
due to the alkalinity input becomes more efficient over time with
increasing ocean acidification. The alkalinity-induced CDR potential scales
linearly with the amount of olivine, while the iron-induced CDR saturates
at 113 PgC per century (on average  PgC yr−1) for an iron input rate of
2.3 Tg Fe yr−1 (1% of the iron contained in 3 Pg olivine). The additional
iron-related CO2 uptake occurs in the Southern Ocean and in the
iron-limited regions of the Pacific. Effects of this approach on surface
ocean pH are small .

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