https://www.seas.harvard.edu/news/2020/12/laboratory-experiments-particles-solar-geoengineering-demonstrate-limits-models

Laboratory experiments on particles for solar geoengineering demonstrate
limits of models
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December 15, 2020
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Injecting light-reflecting aerosols into the stratosphere — known as solar
geoengineering —could be used in conjunction with emissions reduction to
lower the risks of a climate change and cool the planet.  But deliberately
introducing particles into the atmosphere may also carry significant risks,
and those dangers may increase depending on what aerosols are used. Sulfate
aerosols, for example, could contribute to ozone damage and stratospheric
heating.

In 2016, researchers from the Harvard John A. Paulson School of Engineering
and Applied Sciences (SEAS) used computer models to find that calcium
carbonate
<https://www.seas.harvard.edu/news/2016/12/mitigating-risk-geoengineering>
(CaCO3) could not only reflect light and cool the planet but also counter
ozone loss by neutralizing emissions-borne acids in the stratosphere — like
an antiacid for the atmosphere.

Now, the team has conducted the first laboratory experiment to study
calcium carbonate’s reactivity with ozone depleting gasses including
hydrogen chloride (HCl), nitric acid (HNO3), and chlorine nitrate (ClONO2)
under stratospheric conditions and found that calcium carbonate is actually
less chemically active when reacting with those chemicals than previously
thought, meaning it wouldn’t do much to counter ozone loss.

“This research demonstrates that existing computer models are only as good
as the data they built on and they can't do a good job predicting the
impacts and benefits of solar geoengineering without new data from
experiments, which is why laboratory and eventually field experiments are
so important,” said David Keith
<https://www.seas.harvard.edu/person/david-keith>, the Gordon McKay
Professor of Applied Physics at SEAS and Professor of Public Policy at the
Harvard Kennedy School and co-senior author of the paper.

The research is published in the journal Communications Earth and
Environment <https://www.nature.com/articles/s43247-020-00058-7>.

“Our research finds that the unintended side effects of stratospheric ozone
disruption from calcium carbonate geoengineering could be small,” said Zhen
Dai, a PhD student at SEAS and first author of the paper.

“Calcium carbonate appears to be much less reactive than the models
originally predicted but there are additional reactions that we have not
yet studied,” said Frank Keutsch
<https://www.seas.harvard.edu/person/frank-keutsch>, the Stonington
Professor of Engineering and Atmospheric Science at SEAS and Professor of
Chemistry and Chemical Biology and co-senior author of the paper.  “While
we can almost certainly expect calcium carbonate will not have the
stratospheric reactivity of sulfate, the actual stratospheric reactivity is
unknown, which is why we need more lab work, followed by field work.”

“These results still leave many unanswered questions,” said Keith. “But
there’s a wide variety of relatively straightforward experiments that could
significantly reduce uncertainties about solar geoengineering the
stratosphere.”

To that end, Keith, Keutsch and a team of Harvard researchers developed the
Stratospheric Controlled Perturbation Experiment (SCoPEx). If approved by
the independent advisory committee, SCoPEx would inject small amounts of
calcium carbonate into the stratosphere to study whether it reacts as
predicted by models and experiments. The amounts injected would be so small
that they would not pose any physical risks, but as a first step, the
SCoPEx research team has asked the independent SCoPEx Advisory Committee to
review plans for a platform test in Sweden in June 2021. The test would not
be the experiment itself, but rather a test of the SCoPEx platform without
the release of any particles. To learn more about SCoPEx and the proposed
test, visit the SCoPEx website
<https://www.keutschgroup.com/scopex/statements>.

The research is co-authored by Debra K. Weisenstein

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