https://cp.copernicus.org/articles/18/485/2022/
“ Large volcanic eruptions occurring in the last glacial period can be detected 
by their accompanying sulfuric acid deposition in continuous ice cores. Here we 
employ continuous sulfate and sulfur records from three Greenland and three 
Antarctic ice cores to estimate the emission strength, the frequency and the 
climatic forcing of large volcanic eruptions that occurred during the second 
half of the last glacial period and the early Holocene, 60–9 kyr before 2000 CE 
(b2k). Over most of the investigated interval the ice cores are synchronized, 
making it possible to distinguish large eruptions with a global sulfate 
distribution from eruptions detectable in one hemisphere only. Due to limited 
data resolution and large variability in the sulfate background signal, 
particularly in the Greenland glacial climate, we only list Greenland sulfate 
depositions larger than 20 kg km−2 and Antarctic sulfate depositions larger 
than 10 kg km−2. With those restrictions, we identify 1113 volcanic eruptions 
in Greenland and 737 eruptions in Antarctica within the 51 kyrperiod – for 
which the sulfate deposition of 85 eruptions is found at both poles (bipolar 
eruptions). Based on the ratio of Greenland and Antarctic sulfate deposition, 
we estimate the latitudinal band of the bipolar eruptions and assess their 
approximate climatic forcing based on established methods. A total of 25 of the 
identified bipolar eruptions are larger than any volcanic eruption occurring in 
the last 2500 years, and 69 eruptions are estimated to have larger sulfur 
emission strengths than the Tambora, Indonesia, eruption (1815 CE). Throughout 
the investigated period, the frequency of volcanic eruptions is rather constant 
and comparable to that of recent times. During the deglacial period (16–9 ka 
b2k), however, there is a notable increase in the frequency of volcanic events 
recorded in Greenland and an obvious increase in the fraction of very large 
eruptions. For Antarctica, the deglacial period cannot be distinguished from 
other periods. This confirms the suggestion that the isostatic unloading of the 
Northern Hemisphere (NH) ice sheets may be related to the enhanced NH volcanic 
activity. Our ice-core-based volcanic sulfate records provide the atmospheric 
sulfate burden and estimates of climate forcing for further research on climate 
impact and understanding the mechanism of the Earth system.”

GR- correlate ice core D/H and 18O/16O with sulfate and you get a pretty good 
idea of the sensitivity of global/local T to atmospheric SO2 loading?


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