phys.org /news/2022-10-small-sulfate-aerosol-masked-effects.html
<https://phys.org/news/2022-10-small-sulfate-aerosol-masked-effects.html> Small
sulfate aerosol may have masked effects of climate change in 1970s
------------------------------
<https://phys.org/archive/17-10-2022/>

October 17, 2022

by Hokkaido University <https://www.global.hokudai.ac.jp/>

Small sulfate particles of diameters 0.4 µm or less from anthropogenic
sources could have had a cooling effect on the climate in the 1970s, by
triggering cloud formation and reflection radiation.

Global warming and climate change <https://phys.org/tags/climate+change/>
are one of the most pressing issues of this century. It is well known
that carbon
dioxide <https://phys.org/tags/carbon+dioxide/> is the most common
greenhouse gas, but what is less known is that a few anthropogenic aerosols
<https://phys.org/tags/anthropogenic+aerosols/> retard the effects of
greenhouse gases. One such chemical is sulfate, which is more infamous for
its role in acid rain <https://phys.org/tags/acid+rain/>.

A team of scientists led by Professor Yoshinori Iizuka at the Institute of
Low Temperature Science, Hokkaido University, has succeeded in
reconstructing the particle sizes of sulfates deposited in Greenland ice
cores, allowing for an accurate determination of their effect on global
warming. Their findings have been published in the *Journal of Geophysical
Research: Atmospheres*. The research team included Ryu Uemura, Nagoya
University; Naga Oshima, Japan Meteorological Agency; and Shohei Hattori,
Nanjing University.

Until the introduction of regulation in the 1970s, the primary
anthropogenic source of sulfate aerosols was sulfur dioxide from fossil
fuels. While sulfur dioxide <https://phys.org/tags/sulfur+dioxide/> is
still emitted due to various anthropogenic activities, the quantity is much
smaller today.

   - [image: Small sulfate aerosol may have masked effects of climate
   change in 1970s] Concentrations of small-particle sulfates were three
   times higher in the 1970s compared to the 2010s, while the concentrations
   of large-particle sulfates were relatively unchanged. Credit: Yoshinori
   Iizuka, et al. *Journal of Geophysical Research*: Atmospheres. September
   16, 2022
   - [image: Small sulfate aerosol may have masked effects of climate
   change in 1970s] A scanning electron micrograph of a sulfate particle
   from the ice core. Credit: Yoshinori Iizuka, et al. *Journal of
   Geophysical Research: Atmospheres*, September 16, 2022

Sulfates are the main components of acid rain and of pollution that
negatively affects human health. Nevertheless, it is known that sulfate
particles <https://phys.org/tags/sulfate+particles/> have a cooling effect
in the atmosphere, counteracting the effects of carbon dioxide and other
greenhouse gases. However, due to the lack of accurate records, it is
difficult to determine the extent of this cooling effect.

The research team investigated the deposition of sulfate aerosol particles
in ice cores from Greenland. They compared samples from 1973–1975 and
2010–2012. They revealed that sulfate aerosols in 1973–1975 were dominated
by small-particle sulfates—smaller than 0.4 µm—at concentrations three
times higher than those in 2010–2012.

In contrast, there is no significant difference in concentrations of
large-particle sulfates between the two periods. The small-particle
sulfates would have had a larger cooling effect due to their ability to
scatter more radiation than the large-particle sulfates. In addition,
sulfate particles act as cloud condensation nuclei, which lead to the
formation of clouds that reflect radiation away from the earth, cooling it.

The team has thus shown that there was a much higher concentration of small
particle sulfates in the 1970s than previously assumed, thereby inducing
significant counteraction of the effects of global warming. Currently, global
warming <https://phys.org/tags/global+warming/> has already caused an
increase in emissions of marine biogenic sulfates. These emissions must be
taken into account when modeling climate change, to understand their future
effects.
------------------------------
*More information:* Y. Iizuka et al, High Flux of Small Sulfate Aerosols
During the 1970s Reconstructed From the SE‐Dome Ice Core in Greenland, *Journal
of Geophysical Research: Atmospheres* (2022). DOI: 10.1029/2022JD036880
<https://dx.doi.org/10.1029/2022JD036880>

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