https://www.science.org/content/article/ocean-geoengineering-scheme-aces-its-first-field-test

*Author*
Paul Voosen

*16 December 2022*

The balmy, shallow waters of Apalachicola Bay, off Florida’s panhandle,
supply about 10% of U.S. oysters. But the industry has declined in recent
years, in part because the bay is warming and its waters are acidifying
because of rising carbon dioxide (CO2) levels. Things got so bad that in
2020, the state banned oyster harvesting for 5 years. Soon afterward, state
officials encouraged climate scientists to perform an unusual experiment to
see whether they could reverse the changes in the water.

In May, at an Apalachicola estuary, the researchers injected some *2000
liters of seawater enriched with lime,* an alkaline powder and a primary
ingredient in cement that’s derived from chalk or limestone. They showed it
neutralized some of the acidity and, in the process, *drew CO2 out of the
atmosphere.*

*It is the first field demonstration of the technique, called ocean liming,*
that they know of. “It is precious getting this response in a real system,”
says Wade McGillis, an engineer and climate scientist at the University of
Notre Dame who helped lead the work
<https://agu.confex.com/agu/fm22/meetingapp.cgi/Paper/1196208>, which was
presented this week at a meeting of the American Geophysical Union (
https://agu.confex.com/agu/fm22/meetingapp.cgi/Paper/1196208).

The experiment is also a rare test of geoengineering, the controversial
proposition of artificially altering the atmosphere or ocean to counteract
the effects of rising CO2. For ocean geoengineering, “normalizing doing
these experiments is really good,” says Ken Caldeira, a climate scientist
at the Carnegie Institution for Science. Such demonstrations can allay
fears by showing small-scale perturbations do not cause lasting
environmental or ecological damage, he says.

The ocean already blunts the effects of climate change, naturally absorbing
30% of annual carbon emissions. But as it dissolves in the water, the
CO2 combines
with calcium and other ions, depleting them. As a result, the pH of the
waters drops, harming marine life, and CO2 uptake slows. “Alkaline
enhancement” aims to reset the water chemistry.

Liming is one approach. The added calcium hydroxide, or lime, raises the
water’s pH and enables it to sequester more CO2 in the form of calcium
bicarbonate or as carbonate deposited in the shells of sea creatures. In
effect, the liming enhances the way the ocean naturally removes CO2, says
Harald Mumma, an environmental engineering graduate student at Notre Dame.
“We just speed up natural processes and make it happen not on geological
time scales, but on human time scales.”

A 2021 report from the National Academies of Sciences, Engineering, and
Medicine (NASEM) called for $2.5 billion
<https://www.science.org/content/article/draw-down-carbon-and-cool-planet-ocean-fertilization-gets-another-look>
in
ocean geoengineering research in the next decade (
https://www.science.org/content/article/draw-down-carbon-and-cool-planet-ocean-fertilization-gets-another-look),
including field tests of alkaline enhancement. Researchers are facing
limits to what can be learned in the lab, says Débora Iglesias-Rodriguez, a
biological oceanographer at the University of California, Santa Barbara,
and co-author of the NASEM report. The lab can’t show you how a plume of
alkali spreads through ocean waters, how added particles might clump up, or
how the chemicals might affect marine life. For all these reasons, she
says, “We desperately need to go in the field.”

McGillis had worked with officials at the Apalachicola National Estuarine
Research Reserve for several years, studying the oyster decline. When he
mentioned the possibility of a trial, they readily agreed. The Notre
Dame–led team conducted several releases, using a nontoxic dye to follow
the plume. Sampling the water, they first found that pH levels did not
increase too drastically, a relief for researchers who feared it might
disrupt marine life. “We got a really nice small perturbation,” McGillis
says. They conducted one release deeper in the estuary, off a long pier,
where microbial activity had already reduced levels of dissolved CO2 to
about 200 parts per million, compared with more than 400 ppm in the
atmosphere. The lime lowered CO2 levels by another 70 ppm, making room for
more. They also monitored oyster and microbial metabolisms during the trial
and saw no red flags.

Liming is only one possible technique for increasing ocean carbon storage.
In April, researchers from the Centre for Climate Repair at the University
of Cambridge, along with India’s Institute of Maritime Studies, spread
iron-coated rice husks across the Arabian Sea. Iron, a nutrient, is scarce
in much of the ocean; the researchers hoped adding it would fertilize a
bloom of photosynthetic algae, which would soak up carbon and sequester it
when the algae die and sink. Unfortunately, a storm hit soon after the
deployment, stirring up the husks and making their effect difficult to
track. “The result was inconclusive,” says Hugh Hunt, a climate engineer
with the Cambridge team. Since February, researchers have also sought to
capture carbon by cultivating giant kelp off the coast of Namibia—in effect
creating a carbon-hungry submarine forest.

The Florida trial is not the first field test of ocean alkaline
enhancement. In 2014, Caldeira and colleagues added sodium hydroxide—also
known as lye and an ingredient in many soaps and detergents—to a part of
Australia’s Great Barrier Reef. They found it raised pH levels nearly to
preindustrial levels, allowing the natural calcification of the reef to
increase. But the great advantage of lime is that it is already produced at
enormous scales for the cement industry, McGillis says.

Caldeira’s team wrote that its approach would be “infeasible” as a global
solution. That’s because it’s difficult to make alkaline additives without
emitting CO2, he says. Heating limestone to make lime, for example,
releases so much of the gas that it partially offsets the increased uptake
by the ocean. Even if low-emission lime could be made, it would probably be
too costly to dump into the ocean.

But as CO2 continues to rise and geoengineering a climate solution grows
more tempting, ocean liming has a key advantage over other geoengineering
proposals, such as schemes to release sunlight-reflecting particles in the
atmosphere. “Altering the chemistry of seawater is much more controllable
than throwing particles in the air,” McGillis says. Particles can stay in
the stratosphere for months or years. Ocean additives tend to only last a
month before being diluted and dispersed, he says. “There’s much greater
control if it goes south."

*Source*: Science

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