Hi, Introducing chlorine in any form into the stratosphere has potential to greatly affect stratospheric ozone. Nitric and sulfuric acid will liberate HCl from NaCl and this HCl can turn into active forms of chlorine. The chloride in solid NaCl itself can react with ClONO2 to form Cl2 which will destroy ozone. So overall, NaCl is not an ideal material for stratospheric aerosol…
There is not much sea salt aerosol in the stratosphere. Mostly it is sulfuric acid (with some nitric acid depending on conditions such as temperature) and in the lower stratosphere organic and biomass burning aerosol. Frank ___________________________________________________________________________________________ Frank N. Keutsch Stonington Professor of Engineering and Atmospheric Science Harvard John A. Paulson School of Engineering and Applied Sciences Department of Chemistry and Chemical Biology Department of Earth and Planetary Sciences Harvard University 12 Oxford Street Cambridge, MA 02138 USA E-mail: [email protected]<mailto:[email protected]> Tel:+1-617-495-1878 ___________________________________________________________________________________________ From: <[email protected]> on behalf of "[email protected]" <[email protected]> Reply-To: "[email protected]" <[email protected]> Date: Monday, February 27, 2023 at 12:37 PM To: 'geoengineering' <[email protected]> Subject: [geo] impacts of nanoparticle sodium chloride particles at high altitude I am seeking to understand what might be any adverse impacts of delivering salt particles of 20 to 50 nanometres to the high atmosphere (greater than 20 km). The salt particles would be derived from sea water and therefore contain other sea minerals. It is worth pointing out that such particles already exist at this altitude derived from sea sprays. I do not understand the impact of these current particles but I suspect others have already looked at this. I would like to tap into this work. For this discussion, please can we leave aside how these would be delivered to this altitude. I want input on the impact of the fine salt particles and not the delivery. David Sevier Carbon Cycle Limited 248 Sutton Common Road Sutton, Surrey SM3 9PW England Tel 44 (0) 208 288 0128 -- You received this message because you are subscribed to the Google Groups "geoengineering" group. To unsubscribe from this group and stop receiving emails from it, send an email to [email protected]<mailto:[email protected]>. To view this discussion on the web visit https://groups.google.com/d/msgid/geoengineering/020201d94ad2%242f00a7e0%248d01f7a0%24%40carbon-cycle.co.uk<https://urldefense.proofpoint.com/v2/url?u=https-3A__groups.google.com_d_msgid_geoengineering_020201d94ad2-25242f00a7e0-25248d01f7a0-2524-2540carbon-2Dcycle.co.uk-3Futm-5Fmedium-3Demail-26utm-5Fsource-3Dfooter&d=DwMFaQ&c=WO-RGvefibhHBZq3fL85hQ&r=SxgtIVByLvhD8QiO8rgwrvm9f9GML9Drha7439cd21U&m=sik3MrTTHgYjcGSm6KkfTXzc86bzEdnZcZXQpXTRREVozNVAytf2xfwK1QMb2elr&s=MMBzrYj-leulS7yoQGbTBcQsiaaGLx_OD4FeWpRUVQw&e=>. -- You received this message because you are subscribed to the Google Groups "geoengineering" group. To unsubscribe from this group and stop receiving emails from it, send an email to [email protected]. To view this discussion on the web visit https://groups.google.com/d/msgid/geoengineering/50C7B2F6-670A-4C30-A980-023786E5D95F%40seas.harvard.edu.
