https://www.mdpi.com/2073-4433/15/11/1322

*Authors*
by Yangyang Xu, Nathanael P. Ribar, Jeffrey Sachnik, Gunnar W. Schade,
Andrew John Lockley, Yi Ge Zhang, Pengfei Yu, Jianxin Hu and Guus J. M.
Velders

*02 November 2024*

https://doi.org/10.3390/atmos15111322

*Abstract*
Large volcanic eruptions, such as the prehistoric Yellowstone eruption,
induce abrupt global cooling—by some estimates at a rate of ~1 °C/year,
lasting for more than a decade. An abrupt global cooling of several °C—even
if only lasting a few years—would present immediate, drastic stress on
biodiversity and food production. This cooling poses a global catastrophic
risk to human society beyond the immediate and direct impact of eruptions.
Using a simple climate model, this paper discusses the possibility of
counteracting large volcanic cooling with the intentional release of
greenhouse gases. Longer-lived compounds (e.g., CO2 and CH4) are unsuitable
for this purpose, but selected fluorinated gases (F-gases), either
individually or in combinations, could be released at gigaton scale to
offset large volcanic cooling substantially. We identify candidate F-gases
(e.g., C4F6 and CH3F) and derive radiative and chemical properties of
‘ideal’ compounds matching specific cooling events. Geophysical constraints
on manufacturing and stockpiling due to mineral availability are
considered, alongside technical and economic implications based on
present-day market assumptions. The effects and uncertainty due to
atmospheric chemistry related to aerosol injection, F-gases release, and
solar dimming are discussed in the context of large volcanic perturbation.
The caveats and future steps using more complex chemistry–climate models
are discussed. Despite the speculative nature of the magnitude and
composition of F-gases, our conceptual analysis has implications for
testing the possibility of mitigating certain global catastrophic cooling
risks (e.g., nuclear winter, asteroid impact, and glacier transition) via
intentional intervention.
Keywords: geoengineering; counter-geoengineering; simple climate model;
supervolcanic eruptions; fluorinated gases.

*Source: MDPI*

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