As explained in this SendGrid documentation[1] there are ways to send email 
through SendGrid. I assume you are using the Web API, which requires 
authentication for each API call[2]. As explained in this documentation[3], 
these third party services use API keys to authenticate your app and you 
have to add the key to the environment variables section in your app's 
App.yaml file. This is a GitHub link[4] showing a Sample App.yaml file for 
an Application in App Engine Flex environment using SendGrid. 

[1]https://sendgrid.com/blog/5-best-practices-for-using-sendgrid-with-google-app-engine/
[2]https://sendgrid.com/docs/API_Reference/Web_API/using_the_web_api.html#-Authentication
[3]https://cloud.google.com/appengine/docs/flexible/php/sending-messages?hl=ru#adding_client_libraries_and_third-party_api_keys_to_your_app
[4]https://github.com/GoogleCloudPlatform/php-docs-samples/blob/master/appengine/flexible/sendgrid/app.yaml

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