> My setCenter is not working. Can you recommend what I should do?

You could just let KmlLayer do its own thing
   
http://code.google.com/apis/maps/documentation/javascript/overlays.html#KMLLayers
"By default, when displaying a KmlLayer, the map is zoomed and
positioned to show the entirety of the layer's contents"

   map.setCenter(saopaulo)
won't work,  see the docs
   http://code.google.com/apis/maps/documentation/javascript/reference.html#Map
setCenter expects to be given a LatLng object, not a KmlLayer object

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