Daniel, thanks for help. Here is answer:
php script
$return = array();
while ($row = pg_fetch_array($result)) { 
    $return[] = array((int)$row[0],(int)$row[1]);
} 

pg_close($db); 

//var_dump($return);       
echo $data=json_encode($return);
?>
 Result is: [[6,4],[6,5],[7,6],[9,8],[5,9]]


and part of HTML code

function drawChart() {

      var data = new google.visualization.DataTable();
      data.addColumn('number', 'ph');
      data.addColumn('number', 'number');

       var jsonData = $.ajax({
        url: "getData2.php",
        dataType: "json",
        async: false
    }).responseText;

    var obj = JSON.parse(jsonData);
    data.addRows(obj);

I am still having problems with format 'date', because I want to display 
date on hAxis, JSON with date(as string)  looks like:

[[6,"2017-11-05"],[6,"2017-10-30"],[7,"2017-10-29"],[9,"2017-10-28"],[5,"2017-10-27"]]


*How to format dates now in google charts?*


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