On 8/11/15 10:15 PM, Vy Phan wrote:
Dear Dr. Justin and Gromacs User,

Thank you so much for your helps.

When I use charmm36 ff to generate the topology for lipid (DOPC). I got
many warning "Warning :Long bond "
And after get the topology, the total charge is very high (+888 e for DOPC
bilayer have 516 molecular). When I used grompp to generate the .tpr file,
I got the many error like this  :
Error  3379 [file topol_Other_chain_D.itp, line 198252]
  No defaut U-B types
...
Error  2379 [file topol_Other_chain_D.itp, line 98252]
   No default Proper Dih.type
....

What can I do to modified the topology to get the correct charge and  fix
the error ?

I download dopc.itp from Tieleman's website. I run simulation and all
things look fine.  People have experiences, please tell  me the difference
of this topology and the one on the charmm36 force field.


The files Tieleman provides are united-atom structures that may use a different naming convention. They won't have H atoms on the aliphatic groups and there is no .hdb entry for DOPC. The ridiculous net charge you got for DOPC (which is neutral!) should be an indicator that whatever topology you built is utter nonsense. There should also be no warnings about missing parameters, so this is further evidence that the topology is wrong and the "things look fine" assertion seems totally unfounded to me.

If you want to simulate a simple membrane, use CHARMM-GUI to build it. It will be 100% CHARMM compliant and we give you all the necessary input files.

-Justin

--
==================================================

Justin A. Lemkul, Ph.D.
Ruth L. Kirschstein NRSA Postdoctoral Fellow

Department of Pharmaceutical Sciences
School of Pharmacy
Health Sciences Facility II, Room 629
University of Maryland, Baltimore
20 Penn St.
Baltimore, MD 21201

[email protected] | (410) 706-7441
http://mackerell.umaryland.edu/~jalemkul

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