Dear all,

I observed strange EXAFS oscillations in my data up to about 1000 eV beyond the 
K-edge, I would like to share this situation with you and hope to get some 
feedback. Please find attached the athena project file of the data.

The chemical composition of the material is (Fe0.5Cu0.5)Sn5. The EXAFS sample 
was prepared by taking the material equal to 2 absorption lengths at the Cu 
K-edge, mixing it with graphite and pressing into the pellet, which was sealed 
between the Kapton tape.

The measurements were carried out at the Cu K-edge of the material in the 
transmission mode at the beamline 5BM of APS.

Here are my concerns:

(1) In the athena project file, the data files "Cu_S1_scan003" and 
"Cu_S1_scan004" are the two scans of the same sample measured one after the 
other. As can be seen, there are strong oscillations even at 1000 eV from the 
Cu K-edge, which is strange because generally EXAFS oscillations "wash out" as 
we go higher in energy. Nevertheless, the two scans appear reproducible.

(2) Once I removed the sample and remeasured it after some time (because I did 
not believe the previous 2 scans), I found completely different data (i.e., 
data "Cu_S1_scan005").

(3) The Cu reference foil measured simultaneously along with the sample for 
each of these scans appear quite reproducible.

I am puzzled as to what can contribute to such effects. I have never seen such 
effects before.

We can rule out the possibility of beam damage, since I have measured up to 3 
scans (25 min per scan) and they all look reproducible. However, once I remove 
the sample and remeasure it after some time to reproduce the previous 3 scans, 
the scan looks totally different.

Also, we can rule out the chemical instability of the material, since the 
material is quite air-stable.

I have measured a series of samples with this composition and all of them have 
the same effect.

I would very much appreciate your feedback!

Best regards


Helmholtz-Zentrum Berlin für Materialien und Energie GmbH

Mitglied der Hermann von Helmholtz-Gemeinschaft Deutscher Forschungszentren e.V.

Aufsichtsrat: Vorsitzender Dr. Karl Eugen Huthmacher, stv. Vorsitzende Dr. 
Jutta Koch-Unterseher
Geschäftsführung: Prof. Dr. Anke Rita Kaysser-Pyzalla, Thomas Frederking

Sitz Berlin, AG Charlottenburg, 89 HRB 5583

Hahn-Meitner-Platz 1
D-14109 Berlin

Attachment: athena.prj
Description: athena.prj

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