Hi Qiang, There are many papers analyzing Pt SACs on ceria and many of them are able to provide good evidence of Pt-O-Ce coordination. See for example Fig. 5d in this paper and the discussion of the model and fit results.
M. Kottwitz, Y. Li, R. M. Palomino, Z. Liu, Q. Wu, G. Wang, J. Huang, J. Timoshenko, S. D. Senanayake, M. Balasubramanian, D. Lu, R. G. Nuzzo, A. I. Frenkel *Local structure and electronic state of atomically dispersed Pt on nanosized CeO2 support* ACS Catalysis *9*, 8738-8748 (2019) <https://you.stonybrook.edu/frenkel/files/2019/08/Pt-SAC-1.pdf> Regards, Anatoly ******** On sabbatical leave at PSI, Switzerland. ******** ------------------------------------------------------------------- Anatoly I. Frenkel Professor Department of Materials Science and Chemical Engineering (primary appointment) Department of Chemistry (affiliate appointment) * Stony Brook University * Stony Brook, NY 11794 Email: [email protected] <https://mail.bnl.gov/OWA/redir.aspx?C=F6wCGt4adziN6IvpdRQ-rWdgy3Oaoif_x-0ybKTBGBlALcrWeszTCA..&URL=mailto%3ajgchen%40columbia.edu> http://you.stonybrook.edu/frenkel Co-Director and Spokesperson, Synchrotron Catalysis Consortium (SCC) at BNL http://you.stonybrook.edu/scc2 Joint Appointment: Senior Chemist Chemistry Division, *Brookhaven National Laboratory* Upton, NY 11973 Email: [email protected] https://www.bnl.gov/staff/frenkel ------------------------------------------------------------------- On Thu, Feb 8, 2024 at 2:08 PM Qiang <[email protected]> wrote: > Hi everyone, > > I would like to have a discussion about the common EXAFS for single atom > catalysts. It is usually observed that there is only one strong peak around > 1.5A in EXAFS, and it is attributed to the nearest neighbors of O or N. > Take an example of Pt1/CeO2 catalyst. Pt single atom is coordinated with a > few oxygens, i.e., PtOx. These oxygens constitute the first shell of Pt. It > is supposed that these O should also attach to the metal element of the > support (Ce here). So there is also Pt-O-Ce structure. Why it doesnot have > strong scattering peak in EXAFS? Is it that because the Pt-O-Ce formed is > not ordered, or it is actually not a bond just some weak contact? > > Thank you very much. > > Qiang > > _______________________________________________ > Ifeffit mailing list > [email protected] > http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit > Unsubscribe: http://millenia.cars.aps.anl.gov/mailman/options/ifeffit >
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