You may just need to re-apply the thermal paste to the GPU, rather than replace 
the heatsink. The thermal paste transfers the heat from the processor to the 
heatsink, but it dies out over time and stops functioning properly. 
Unfortunately the heatsink on those models in on the back of the logic board, 
so anything you do will require a full disassembly. Because re-appling the 
thermal paste is not gauranteed to work, you may just want to replace the 
heatsink at the same time and save yourself the potential of having to do the 
job twice.

Regarding the CCFL backlight, it is theretically possible to replace, but is 
extremely difficult. You are probably better off replacing the entire display 
assembly. If you really want to give it a try, there is a guide on how to do 
this on iFixit:

https://www.ifixit.com/Guide/Removing+CCFL+from+iMac+20in+LCD+CCFL+assembly/5865

Regarding bootcamp, Windows 7 is definitely available in a 32-bit version; I 
know because I have a copy. However, you may still be able to run 64-bit 
Windows on that machine. I have a 2006 Mac Pro which also uses a 32-bit EFI and 
can therfore only run 32-bit Mac OS X, but it is able to run 64-bit Windows via 
bootcamp. I'm not sure this applies to your machine as well, but it's something 
to think about. However, I would say that unless you're using windows for 3D 
gaming, you'll be fine with Paralells or Ware, and in my experience they are a 
lot easier to deal with than boot camp.

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