>If it originally went to domain.com and postfix-01.domain.com is priority
>10 for that domain,  when my script goes to mail them their false-positive,
>it just gets caught again.

The DNS MX record is used by SMTP client to route mail to IMGate.

Once the mail is in IMGate, postfix SMTP client (after any re-writing) then 
resolves next-hop for the recipient domain by:

$mydestination
transport.map
relayhost
hosts
DNS

(well, that's how I think the sequence is. :) )

Your problem seems to be that postfix is resolving domain.com in DNS, so 
"best MX for domain.com is local".

So put domain.com in transport.map.

Len


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