Very much appreciate your finding that, Xavier. We did a lot of testing 
of that, but it's still possible that there is a bug there. I will 
definitely look into it immediately.

By the way, you can deliver those cube files as JVXL format surfaces 
with very little files space if you want to.
http://chemapps.stolaf.edu/jmol/docs/misc/JVXL-format.pdf


Xavier Prat-Resina wrote:

> Jmol developers,
>
> it's seems that Jmol is not able to display the right shape of
> some Molecular Orbitals when the data is read form Gaussian outputs 
> (not cube files).
> This anomaly can already be seen in
> http://chemapps.stolaf.edu/jmol/docs/examples-11/isosurface.htm
> when it loads "water-G03W.out" and the 6th MO has the wrong shape.
>
> I tested it myself comparing it with cube files
> (for water, the discrepancy starts at MO=6)
> http://144.92.39.89/xavier/mo/index.html
> (for ethyne the very first MO is not symmetric)
> http://144.92.39.89/xavier/mo/ethyne.html
>
> It seems to me that Jmol has problems with the d functions,
> labeled in Gaussian as XX, YY, ZZ, XY, XZ, YZ (just a guess).
> For water or ethyne this basis set is used with keywords like 6-31g(d)
> For third or higher row elements, these d functions are always
> included (with the exception of sto-3g basis)
> I tested this for Br:
> http://144.92.39.89/xavier/mo/brf5.html
>
> I've been looking at the source code but I have no clue where the 
> problem is.
> I would be willing to do it myself if I get a hint :)
> Is there any standard/XML format for molecular properties such
> as vibrations, molecular orbitals etc? This would save Jmol a lot
> of trouble when reading formatted files.
>
> Thanks for your help
>
>
> Xavier
>
> -- 
> Xavier Prat-Resina
> Research Associate
> Journal of Chemical Education and University of Wisconsin
> 209 N. Brooks St. Madison, WI  53715-1116
>
> Tel: 608 8901702 // Fax: 608 2627145
> e-mail: xavier.prat.resina + gmail.com <http://gmail.com>; skype: 
> xavierprat
> http://x.prat.resina.googlepages.com
>
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>


-- 
Robert M. Hanson
Professor of Chemistry
St. Olaf College
Northfield, MN
http://www.stolaf.edu/people/hansonr


If nature does not answer first what we want,
it is better to take what answer we get. 

-- Josiah Willard Gibbs, Lecture XXX, Monday, February 5, 1900



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