May this is of some help, 
I use to bundle the jar into double clickable mac app using the instructions in 
http://www.devdaily.com/apple/mac/java-jar-bundler/ nevertheless this does not 
solve the working dir issue.
I think that the working dir issue is related to the java code itself an its 
interaction with the system variables, something of a more general nature, as 
indicated in 
http://www.devdaily.com/blog/post/java/how-determine-directory-java-application-run-from
  May be someone with some acquaintance with java programming can test this...

Greetings
        F.J. Modrego


> 
> 
> Message: 2
> Date: Sat, 15 Jan 2011 17:57:47 -0500
> From: Eric Martz <[email protected]>
> Subject: [Jmol-users] Jmol.app default dir in OS X?
> To: [email protected]
> Message-ID: <[email protected]>
> Content-Type: text/plain; charset="us-ascii"; format=flowed
> 
> Could someone please explain to me how, in OS X (I am using leopard), 
> to most easily set the Jmol.app default directory? The only ways I 
> have found are so cumbersome that I have ended up littering my 
> directory tree with many copies of (different versions of) Jmol.app. 
> I double click on Jmol.app in the directory that has the relevant 
> scripts and PDB files.
> 
> Ideally, I would like a button in Finder that would start Jmol.app, 
> setting the current directory to the one current in Finder. "Open 
> Terminal Here" is an application/droplet/script that does this for 
> Terminal -- not sure if it could be modified to open Jmol.app.
> 
> Second best would be a way to drag and drop, or copy and paste, a 
> directory path that I have located in Finder. If I could easily copy 
> that path to the clipboard, then I could paste it into the Jmol 
> Script Console after typing "cd ". I don't know how to copy a path 
> from Finder to the clipboard.
> 
> Obviously, I don't want to have to hand-type the filepath into a Jmol 
> cd command.
> 
> Thanks! -Eric
> 
> 

Dr. F.J. Modrego
Department of Inorganic Chemistry
Facultad de Ciencias
University of Zaragoza
50009 ZARAGOZA
SPAIN
Tel <34>-976-762288
Fax <34>-976-761187
E-mail:  [email protected]


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