Aha, there it is:
http://sourceforge.net/p/jmol/code/HEAD/tree/trunk/Jmol/src/org/jmol/a
dapter/smarter/Resolver.java
line 573:
// Test 4. One of the first 16 lines starts with one of these strings
[snip]
private final static String[] mmcifLineStartRecords =
{ "MMCif", "_entry.id", "_database_PDB_", "_pdbx_",
"_chem_comp.pdbx_type", "_audit_author.name", "_atom_site." };
You need one of those within the first 16 lines
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