Thanks Bob,

You are correct. A quick web search shows that the ketene oxygen appears to be 
less negative than in formaldehyde and acrolein. With a publication that 
describes this, comparison of ketene and acrolein in Jmol with hybridized 
orbitals is a nice little model kit exercise.

Otis

--
Otis Rothenberger
[email protected]
http://chemagic.com

> On Sep 20, 2015, at 9:50 PM, Robert Hanson <[email protected]> wrote:
> 
> I'm pretty sure ketene's oxygen is sp hybridized in order to delocalize into 
> both (perpendicular) pi systems. 
> 
> You need 
> 
> load $ketene
> select _O
> lcaocartoon molecular "py"
> lcaocartoon molecular "pz"
> lcaocartoon molecular "spb"
> 
> Bob
> 

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