The quadrature rules for simplices in libmesh have been recently 
refurbished I think (thanks John!) and with that in mind I thought I'd 
just pass on a link to a new paper I saw about this topic:

Linbo Zhang, Tao Cui and Hui Liu
A Set of Symmetric Quadrature Rules on Triangles and Tetrahedra.
J. Comp. Math., 27 (2009), pp. 89-96.
http://www.global-sci.org/jcm/volumes/v27n1/pdf/271-89.pdf

It's got a nice description of their algorithm for finding symmetric 
quadrature rules, and they list a bunch of them. However, happily, their 
quadrature rules don't offer much of an improvement over the ones 
already available in libMesh (except that they have explicitly found 
quadrature rules on tets up to order 14).

- Dave

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