RFC 2396:
2.3. Unreserved Characters
Data characters that are allowed in a URI but do not have a reserved
purpose are called unreserved. These include upper and lower case
letters, decimal digits, and a limited set of punctuation marks and
symbols.
unreserved = alphanum | mark
mark = "-" | "_" | "." | "!" | "~" | "*" | "'" | "(" | ")"
Unreserved characters can be escaped without changing the semantics
of the URI, but this should not be done unless the URI is being used
in a context that does not allow the unescaped character to appear.
So IE/Mozilla escape '!' in application/x-www-form-urlencoded forms.
Do they treat any other of the mark chars the same way?
