`
New transistor’s superlative properties could have broad electronics 
applications

Ultrathin material whose properties “already meet or exceed industry standards” 
enables superfast switching, extreme durability.


By Elizabeth A. Thomson  |  Materials Research Laboratory Publication   |   
Date: July 26, 2024
https://news.mit.edu/2024/new-transistors-superlative-properties-could-have-broad-electronics-applications-0726

{Image Caption: Schematic showing the crystal structure of the boron nitride 
key to a new ferroelectric material that MIT researchers and colleagues have 
used to build a transistor with superlative properties.]


In 2021, a team led by MIT physicists reported creating a new ultrathin 
ferroelectric material, or one where positive and negative charges separate 
into different layers. 

At the time they noted the material’s potential for applications in computer 
memory and much more. 

Now the same core team and colleagues — including two from the lab next door — 
have built a transistor with that material and shown that its properties are so 
useful that it could change the world of electronics.


Although the team’s results are based on a single transistor in the lab, “in 
several aspects its properties already meet or exceed industry standards” for 
the ferroelectric transistors produced today, says Pablo Jarillo-Herrero, the 
Cecil and Ida Green Professor of Physics, who led the work with professor of 
physics Raymond Ashoori. Both are also affiliated with the Materials Research 
Laboratory.

“In my lab we primarily do fundamental physics. This is one of the first, and 
perhaps most dramatic, examples of how very basic science has led to something 
that could have a major impact on applications,” Jarillo-Herrero says.

Says Ashoori, “When I think of my whole career in physics, this is the work 
that I think 10 to 20 years from now could change the world.”

Among the new transistor’s superlative properties:

* It can switch between positive and negative charges — essentially the ones 
and zeros of digital information — at very high speeds, on nanosecond time 
scales. (A nanosecond is a billionth of a second.)

* It is extremely tough. After 100 billion switches it still worked with no 
signs of degradation.

* The material behind the magic is only billionths of a meter thick, one of the 
thinnest of its kind in the world. That, in turn, could allow for much denser 
computer memory storage. It could also lead to much more energy-efficient 
transistors because the voltage required for switching scales with material 
thickness. (Ultrathin equals ultralow voltages.)


The work is reported in a recent issue of Science. The co-first authors of the 
paper are Kenji Yasuda, now an assistant professor at Cornell University, and 
Evan Zalys-Geller, now at Atom Computing. Additional authors are Xirui Wang, an 
MIT graduate student in physics; Daniel Bennett and Efthimios Kaxiras of 
Harvard University; Suraj S. Cheema, an assistant professor in MIT’s Department 
of Electrical Engineering and Computer Science and an affiliate of the Research 
Laboratory of Electronics; and Kenji Watanabe and Takashi Taniguchi of the 
National Institute for Materials Science in Japan.  
https://www.science.org/doi/10.1126/science.adp3575

What they did

In a ferroelectric material, positive and negative charges spontaneously head 
to different sides, or poles. Upon the application of an external electric 
field, those charges switch sides, reversing the polarization. Switching the 
polarization can be used to encode digital information, and that information 
will be nonvolatile, or stable over time. It won’t change unless an electric 
field is applied. For a ferroelectric to have broad application to electronics, 
all of this needs to happen at room temperature.

The new ferroelectric material reported in Science in 2021 is based on 
atomically thin sheets of boron nitride that are stacked parallel to each 
other, a configuration that doesn’t exist in nature. In bulk boron nitride, the 
individual layers of boron nitride are instead rotated by 180 degrees.

https://news.mit.edu/2021/physicists-engineer-ferroelectricity-in-boron-nitride-0915

It turns out that when an electric field is applied to this parallel stacked 
configuration, one layer of the new boron nitride material slides over the 
other, slightly changing the positions of the boron and nitrogen atoms. 

For example, imagine that each of your hands is composed of only one layer of 
cells. The new phenomenon is akin to pressing your hands together then slightly 
shifting one above the other.

“So the miracle is that by sliding the two layers a few angstroms, you end up 
with radically different electronics,” says Ashoori. The diameter of an atom is 
about 1 angstrom.

Another miracle: “nothing wears out in the sliding,” Ashoori continues. That’s 
why the new transistor could be switched 100 billion times without degrading. 

Compare that to the memory in a flash drive made with conventional materials. 
“Each time you write and erase a flash memory, you get some degradation,” says 
Ashoori. “Over time, it wears out, which means that you have to use some very 
sophisticated methods for distributing where you’re reading and writing on the 
chip.” 

The new material could make those steps obsolete.

A collaborative effort

Yasuda, the co-first author of the current Science paper, applauds the 
collaborations involved in the work. 

Among them, “we [Jarillo-Herrero’s team] made the material and, together with 
Ray [Ashoori] and [co-first author] Evan [Zalys-Geller], we measured its 
characteristics in detail. That was very exciting.” Says Ashoori, “many of the 
techniques in my lab just naturally applied to work that was going on in the 
lab next door. It’s been a lot of fun.”

Ashoori notes that “there’s a lot of interesting physics behind this” that 
could be explored. 

For example, “if you think about the two layers sliding past each other, where 
does that sliding start?” 

In addition, says Yasuda, could the ferroelectricity be triggered with 
something other than electricity, like an optical pulse? 

And is there a fundamental limit to the amount of switches the material can 
make?

Challenges remain. For example, the current way of producing the new 
ferroelectrics is difficult and not conducive to mass manufacturing. 

“We made a single transistor as a demonstration. If people could grow these 
materials on the wafer scale, we could create many, many more,” says Yasuda. 

He notes that different groups are already working to that end.

Concludes Ashoori, “There are a few problems. But if you solve them, this 
material fits in so many ways into potential future electronics. It’s very 
exciting.”

This work was supported by the U.S. Army Research Office, the MIT/Microsystems 
Technology Laboratories Samsung Semiconductor Research Fund, the U.S. National 
Science Foundation, the Gordon and Betty Moore Foundation, the Ramon Areces 
Foundation, the Basic Energy Sciences program of the U.S. Department of Energy, 
the Japan Society for the Promotion of Science, and the Ministry of Education, 
Culture, Sports, Science and Technology (MEXT) of Japan.

Paper: "Ultrafast high-endurance memory based on sliding ferroelectrics"

By Raymond Ashoori
Ashoori Group @ MIT
Pablo Jarillo-Herrero
Jarillo-Herrero Group

Materials Research Laboratory
Department of Physics  
School of Science

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