Am 22.11.2010 13:22, schrieb Taco Hoekwater:

The problematic case seems to be: a combination of a non-letter in one
font, followed by a letter in another font. LuaTeX does not consider
that a valid word start. I will add an item to the tracker database.

There's another problem with fontspec and hyphenation involving only letters, but font switching, too. You can find the (short) discussion on lualatex-dev at <URL:http://permalink.gmane.org/gmane.comp.tex.lualatex.devel/556>.

Best regards,
Stephan Hennig

\documentclass[draft]{article}
\usepackage{fontspec}
\usepackage[width=2cm]{geometry}
\begin{document}
An  intere\textit{st}ing word.% no hyphenation

An intere{\itshape st\/}ing word.% hyphenated
\end{document}

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