Well ok, I did some additional debugging on my debian machine and recognized 
that postfix did not write to /var/log/mail.log. I just installed missing 
rsyslog and then I got output from postfix to /var/log/mail.log.
The log told me that my relaying host is replying with "unable to relay". After 
some further investigations I just recognized one missing config on my relaying 
host which is managing the permissions for outgoing mails.
Sorry for the confusion, the email delivery is now working fine.

Thank you also for the super-fast responses!
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