Dear colleagues,
I hope this message findsyou well. 

Iam pleased to share two new contributions on food-web bioaccumulation 
modelingfor anthropogenic pollutants using marine mammalian food webs. Please, 
seebelow: Modeling 137Cs bioaccumulation inthe salmon–resident killer whale 
food web of the Northeastern Pacific followingthe Fukushima Nuclear Accident 
Science ofThe Total EnvironmentVolume 544, 15 February2016, Pages 
56–67doi:10.1016/j.scitotenv.2015.11.097 Juan José Alava& Frank A. P. C. Gobas
Abstract
To track the longterm bioaccumulation of 137Cs in marine organisms off the 
PacificNorthwest coast of Canada, we developed a time dependent bioaccumulation 
modelfor 137Cs in a marine mammalian food web that included fish-eatingresident 
killer whales. The model outcomes show that 137Cs can beexpected to gradually 
bioaccumulate in the food web over time as demonstratedby the increase of the 
apparent trophic magnification factor of 137Cs,ranging from 0.76 after 1 month 
of exposure to 2.0 following 30 yearsof exposure. 137Cs bioaccumulation is 
driven by relatively rapiddietary uptake rates, moderate depuration rates in 
lower trophic levelorganisms and slow elimination rates in high trophic level 
organisms. Modelestimates of the 137Cs activity in species of the food web, 
based oncurrent measurements and forecasts of 137Cs activities in oceanicwaters 
and sediments off the Canadian Pacific Northwest, indicate that the longterm 
137Cs activities in fish species including Pacific herring,wild Pacific salmon, 
sablefish and halibut will remain well below the current 137Cs-CanadaAction 
Level for consumption (1000 Bq/kg) following a nuclear emergency.Killer whales 
and Pacific salmon are expected to exhibit the largest long term 
137Csactivities and may be good sentinels for monitoring 137Cs in theregion. 
Assessment of the long term consequences of 137Cs releasesfrom the Fukushima 
aftermath should consider the extent of ecologicalmagnification in addition to 
ocean dilution.
Alava, J. J., Gobas, F. A. 2016. Modeling 137Cs bioaccumulation in the 
salmon-resident killerwhale food web of the Northeastern Pacific following the 
Fukushima NuclearAccident. Science of the Total Environment 544: 
56-67doi:10.1016/j.scitotenv.2015.11.097 Free access to this articleis 
available from the following link and valid for 50 days, until January 22,2016:

http://authors.elsevier.com/a/1S8a5B8ccV62y Alternatively,it can be found 
at:https://www.researchgate.net/profile/Juan_Jose_Alava/contributions Food Web 
BioaccumulationModel for Resident Killer Whales from the Northeastern Pacific 
Ocean as a Toolfor the Derivation of PBDE-SedimentQuality Guidelines.

Archives of EnvironmentalContamination and ToxicologyFirstonline: 20 August 
2015 pp 1-14
doi:10.​1007/​s00244-015-0215-y Juan José Alava, Peter S. Ross & Frank A. P. C. 
Gobas
Abstract
Residentkiller whale populations in the NE Pacific Ocean are at risk due to 
theaccumulation of pollutants, including polybrominated diphenyl ethers 
(PBDEs).To assess the impact of PBDEs in water and sediments in killer whale 
criticalhabitat, we developed a food web bioaccumulation model. The model was 
designedto estimate PBDE concentrations in killer whales based on PBDE 
concentrationsin sediments and the water column throughout a lifetime of 
exposure. Calculatedand observed PBDE concentrations exceeded the only toxicity 
reference valueavailable for PBDEs in marine mammals (1500 μg/kg lipid) in 
southernresident killer whales but not in northern resident killer whales. 
Temporaltrends (1993–2006) for PBDEs observed in southern resident killer 
whales showeda doubling time of ≈5 years. If current sediment quality 
guidelinesavailable in Canada for polychlorinated biphenyls are applied to 
PBDEs, it canbe expected that PBDE concentrations in killer whales will exceed 
availabletoxicity reference values by a large margin. Model calculations 
suggest that aPBDE concentration in sediments of approximately 1.0 μg/kg dw 
producesPBDE concentrations in resident killer whales that are below the 
currenttoxicity reference value for 95 % of the population, with this 
valueserving as a precautionary benchmark for a management-based approach 
toreducing PBDE health risks to killer whales. The food web bioaccumulation 
modelmay be a useful risk management tool in support of regulatory protection 
forkiller whales. Alava, J.J., Ross, P.S., Gobas, A.P.C. 2015. Food web 
bioaccumulationmodel for resident killer whales from the Northeastern Pacific 
Ocean as a toolfor the derivation of PBDE-Sediment Quality Guidelines. Archives 
of EnvironmentalContamination and Toxicology. doi: 10.​1007/​s00244-015-0215-y 
The article can be found at 
https://www.researchgate.net/publication/280740512_Food_Web_Bioaccumulation_Model_for_Resident_Killer_Whales_from_the_Northeastern_Pacific_Ocean_as_a_Tool_for_the_Derivation_of_PBDE-Sediment_Quality_Guidelines
Or obtained from the publisher: 
http://link.springer.com/article/10.1007/s00244-015-0215-y?wt_mc=internal.event.1.SEM.ArticleAuthorOnlineFirst#
 Best Wishes!!! Juan José Alava
 -----------------------------------------------------------------------Juan 
Jose Alava, PhD  
Adjunct Professor
Resource and Environmental Management, Faculty of Environment, 
Simon Fraser University
8888 University Drive, 
Burnaby, British Columbia V5A 1S6,Canada
E-mail: [email protected] 
https://www.researchgate.net/profile/Juan_Jose_Alava/contributions?ev=prf_act

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