For those of you who don't know what you're looking at in this picture, here is a little explanation.

All of the colored bars and the circular rim in this picture are the mineral olivine. The black stuff in between the bars is either feldspathic glass (possible if this is a highly unequilibrated chondrite) or microcrystalline material that probably was once glassy. The image is taken with two polarizers, one below the thin section and another above it, with the two polarizers rotated 90 degrees to each other (petrographers call this crossed polarizers).

Some minerals are isotropic and some are anisotropic. Isotropic minerals have the same optical properties in all directions. If you put a thin section of such a mineral between crossed polars, it will look black. The glass in chondrules is isotropic, so it looks black in this photo. However olivine is anisotropic: its index of refraction is not the same in every direction. When viewed between crossed polarizers, interference colors are seen. This property is called birefringence. Olivine has a relatively high birefringence, which is why it appears to have gaudy colors in photos of standard thin sections like this, compared to minerals like pyroxene or feldspar, which are much less birefringent (but not isotropic) and would appear white to gray.

The exact color of an individual grain depends on several factors. One is the thickness of the section. A change of a few micrometers in thickness could give the effect seen in this photo. Such a large change over the distance of a few hundred micrometers would indicate this a really badly made thin section, and it would be obvious to the owner. I assume it is not this. The birefringence of olivine is also a weak function of composition; it would take a large Fe-Mg gradient to give you an effect like this. This is almost certainly not the case. Zoning from side-to-side in chondrules is basically unknown in chondrites; it is almost always radial. The other, and almost certainly the correct explanation for the color change is that the orientation of the crystal changes slightly across the chondrule. A small amount of deformation, perhaps due to light shock, or perhaps due to the way the olivine crystallized, could easily cause this effect. The highly fractured nature of the olivine (see all the little transverse cracks), is consistent with shock. The deformation may also have taken place during production of the thin section, if the section buckled a tiny bit.

jeff

At 12:36 PM 10/2/2007, [EMAIL PROTECTED] wrote:
Hello again,

I just got mail from Marc Fries. Thank you, Marc! Very much
appreciated. Now, Marc prefers option #3 and so he writes:

"I was thinking option 3), myself. It only takes a thickness variation
 on the order of 100 nanometers or so to get that color gradient, and
 if it were chemical I'd expect a change in the rim vs. the interior rather
 than an uniform gradient across the chondrule."

Rather convincing! Why should the chemical composition within a single
BO chondrule change *gradually*... especially in view of the fact that the
bars are oriented identically!

Best wishes,

Bernd

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Dr. Jeffrey N. Grossman       phone: (703) 648-6184
US Geological Survey          fax:   (703) 648-6383
954 National Center
Reston, VA 20192, USA


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