Ni-free metal occurs within chondrules that have experienced reduction during melting. These chondrules were originally mostly free of metal and therefore free of Ni, but contained oxidized iron (FeO) in the silicate minerals. During reduction, the FeO was converted into Fe metal (if the reducing agent was H2, then you'd also make H2O; if it was C then you'd make CO/CO2). The pure Fe metal that is made can manifest itself as "dusty metal" grains within olivine crystals, or sometimes can coalesce into larger Fe metal particles in the chondrule.

The thing about this is, it is a local effect within a few chondrules. Most of the metal in the chondrite is still Ni-bearing. There is no easy way to make large masses of this pure Fe metal, such as would form iron meteorites, because any process that would segregate metal, would segregate all of it, not just these strange particles.

Jeff

On 2010-03-25 5:59 PM, [email protected] wrote:
List,
During recent research into CBb chondrites I stumbled upon an article from 2007 
with references from Rubin  that shows an image of a CC chondrite with nickel 
free metal.
How is this possible?
In past conversations with Scientists when I have asked why do iron meteorites 
always have to have nickel. The typical response is that they not only have to 
have nickel but, it has to have a few percent of nickel and not just PPM's of 
it. In explanation of this as I recall, I've always been told the reason  that 
meteoritic iron always has to have Nickel is because in nature there is no way 
to separate the two elements.
If that is true then how is it that in this case we do in fact have meteoritic 
metal without nickel? somehow they got separated.
Unless this analysis is wrong does this not teach us that yes in fact there can 
and does exist meteoritic iron devoid of nickel. And therefore there not only 
could be Iron meteorites without nickel but,this ups the odds that there in 
fact are meteorites without nickel.
Please see attached abstract. Back scattered images Figure 2 at the fifth page 
from the top of the article. It says;
"D. Close up of a CC Chondrule texture. Radiating unidentified minerals and Nickel 
free metal (met) are set up in a silica-rich matrix."

http://www2.mnhn.fr/hdt205/leme/doc/2007%20Gounelle%20et%20al.%20EPSL.pdf

Thanks Carl

--
Carl or Debbie Esparza
Meteoritemax
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--
Dr. Jeffrey N. Grossman       phone: (703) 648-6184
US Geological Survey          fax:   (703) 648-6383
954 National Center
Reston, VA 20192, USA


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