No worries....your tubes are 100% safe.
Even though some materials used in a vacuum tube might be classified as 
semiconductors, they dont operate in that manner.

Tubes conduct electrons through a vacuum or gas; solid-state devices (aka 
semiconductors) conduct thru, guess what, solids.

But, I do wonder how the density of atoms in a typical vacuum tube compares 
to the density of impurities in a doped semiconductor.

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