Bombarding is one way to bake-out impurities in the glass, electrodes, 
phosphor, etc in a neon tube. Generally it's done using a current-limited 
high-voltage source, running at a much higher current (hundreds of 
milliamps, which is deadly) than normal operation (20-50mA, depending upon 
tube diameter). From what I recall, bombarding is started once the vacuum 
is around a few torr and the current is adjusted until the glass reaches a 
high temperature (around 500F I think), during which the electrodes will be 
almost red-hot. As the gas heats up, the pressure will increase and you 
continue pumping to remove the impurities as well as maintain bombarding 
current.

I recommend reading-up on Paschen's Law, which describes how the ionization 
voltage decreases with pressure until a minimum is reached, and then 
increases as pressure is lowered further.

As the pressure is lowered below 1 torr at high temperature, the impurities 
are released and drawn out thru the vacuum port. This is where things can 
get really scary, because I've heard of cases where flashover occurs and an 
arc will go thru the neon work, into your manifold (multiport section for 
managing your pump, fill-gas, vacuum gauge, etc), and thru the pump. Yikes. 
Most setups I've read about use a 2-stage mechanical pump for the primary 
pump-down, and a diffusion pump to get below 1 torr. You also need good 
vacuum gauges. You can easily spend over $2000 US on the equipment.

I also recommend reading about diffusion pumps; I never heard about them 
before researching neon work.

After some amount of time, the bombarding is stopped and the glasswork 
cools, the vacuum is continued and I think I've seen people going down to 
50 microns. Then the fill gas is introduced and pressurized to get optimum 
glow. Some mixtures require mercury; I'm not sure how they introduce it 
into the tube. Finally, the tubulation (electrode with a glass connector) 
is tipped-off and the tube is run for several hours to make sure it's 
properly filled, etc.

It's really amazing how much work goes into a neon-sign tube.

There are several good books on neon; See "Neon Techniques" by Strattman.
"Neon Engineer's Notebook" (Fishman & Crook) is very good; I was able to 
get a personally signed copy

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