Im not making them out of FR4 because of the glass fibers freed by 
machining i dont have a way to contain

the XXX paper phenolic is still really good (fr4 has a dielectric of 
800V/mil and XXX paper has 700V/mil, the LE phenolic which is more 
structural has 650V/mil)

but if your looking at surface resistivity, yes PTFE is by far the leader. 
here is a table of different laminates and their 
data http://www.plasticsintl.com/sortable_materials.php

from what ive been reading XXX paper phenolic is fine for RF applications

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