Doesn't sound like cathode-poisoning.  Are you able to observe the straps 
welded to the individual pins ? Making a tube this size in a production 
environment is not trivial, so it's possible the weld broke, got dirty, etc.

You mentioned going up to 300V; that's plenty enough because the '1' is 
usually at the very bottom of the stack and works on both tubes. 
Theoretically, that should be the most difficult to illuminate as it's 
furthest from the anode mesh. '3' is on the top for my 5092 & 6091, and 
probably for your tubes. Most likely it's an open circuit.

Do you have a capacitance meter ? You could try measuring capacitance 
between various cathodes to see if the dead digits have unusually low 
capacitance. That would bolster the broken connection theory. Come to think 
of it, I dont remember if I've ever tried measuring capacitance on my tubes 
so I'm not sure what kind of values to expect. Probably in the low pF range.

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