In terms of longevity provided by mercury one just need look at the Chinese 
QS27-1 and QS30-1 tubes that contain no mercury. They are known to have 
very short lives. I also understand that Russian tubes prior to the IN-7, 
which does contain mercury, also have very short lifespans. I see a lot of 
the IN-1, IN-2 and IN-4 tubes on eBay at relatively low prices compared to 
the higher numbered tubes. I am guessing the demand is not there because of 
their failure rate or they have to discount them because they will fail.

On Friday, July 17, 2020 at 1:27:39 PM UTC-4, Paul Andrews wrote:
>
> I recently saw a post that suggested that the addition of a mercury dopant 
> to Nixie tubes does not confer the protection that we have all been led to 
> believe - apparently the Russians made a study suggesting this to be the 
> case. 
>
> Regardless of whether this is true or not, I was wondering if there is a 
> way to determine the presence of mercury in tubes experimentally in a 
> non-destructive way, for example by using a spectrometer. If so, it might 
> be interesting to test a sample of tubes, including some that were 
> developed later, to see if they really do contain mercury. The presence of 
> mercury wouldn’t be conclusive evidence of its effectiveness, but the 
> absence could lend credence to the argument. It would be interesting 
> information either way. 
>
> I know that some of you will say that you can see a tell-tail blue glow, 
> but I have quite a few nixies, including later examples, that do not show 
> this. I wouldn’t take this as proof that those tubes don’t contain mercury, 
> it could just be smaller amounts. 
>
> This also got me thinking; if it isn’t mercury that confers a longer life, 
> then could it be something else? Could it be fine-tuning the cathode 
> material? Could it be fine tuning of the gas mixture and/or pressure? Which 
> got me wondering if there would also be a way to determine the pressure in 
> the tube? For example by examining the width of spectral emission lines?

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