There is no default way.  You cannot schedule it in the task scheduler and you have to 
be a admin to run it.  A couple solutions one go and Diskeeper or some other third 
pary app.  Also I have found freeware called Autodefrag where you can through the task 
scheduler but the user will have to have admin priveleges.  You can find autodefrag at 
www.morphasys.com.

http://www.sunbelt-software.com/ntsysadmin_list_charter.htm

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