Andrew Dalke wrote:
> On Dec 14, 2009, at 9:28 PM, Geoffrey Hutchison wrote:
>> Craig, do you have another solution? Is there a wild-card or dummy atom for 
>> the canonical SMILES?
> 
> I haven't been tracking this, so just a reflex action pointing out "*".

As Andrew points out, "*" is a possible choice.  I don't know the exact problem 
you're trying to solve, but the advantage of "*" is that if you copy the 
H-count and/or charge, the SMILES writer won't try to monkey with it, and will 
just write it out exactly as you specify.  Unlike carbon, "*" has no valence 
assumptions.

(Sorry for the delay answering ... been moving to a new place, just unpacked 
the computer.  Also accidentally replied to Andrew only the first try.)

Craig


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