> I wonder that is it possible to indentify atoms by indecies ( ie. atom
> number in xyz file) with SMART pattern? I am trying to fit two molecules
> with OBFIT and would like to do it by atom number.  

Well, you can script the fitting, but it wouldn't be by OBFIT or SMARTS 
pattern, because those don't consider atom indices.

But there are multiple ways to align if you have a set of atoms. I'd suggest 
looking at the tools/obfit.cpp code yourself -- the key bit is the call to 
qtrfit() which just takes an array of coordinates for the alignment.

-Geoff
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