Does your pH meter have a temperature compensation function?
Paul

-------------- Original message -------------- 

> Olga Caussade asked why her water has a pH of 6.5 when stored in the dark, 
> but has a pH of 5 and is 10 degrees C warmer when kept in the light. 
> 
> Olga, I tried doing the maths & your numbers didn't work out. Basically, the 
> pH of any sample of water varies with the temperature. As the temperature 
> rises, the pH decreases because the solution becomes more acidic, and it 
> becomes less acidic as the temperature falls, which is what you observed. 
> Unfortunately, you'd need a hell of a lot more than a 10 degree rise to drop 
> the pH by 1.5 degrees, so something else must be happening in your water. 
> 
> Water always contains dissolved carbon dioxide, which makes it acidic. As 
> the temp rises, less carbon dioxide dissolves, so the pH rises (water 
> becomes less acidic). This effect runs in the opposite direction to the 
> pH/temperature effect, and if my assumptions about your water and maths are 
> right, this would more or less cancel out the drop in pH caused by your 10 
> degree temp rise. 
> 
> Conclusion; something else is causing your pH change. Have you got any algae 
> or other plants growing in your container ? They would proliferate in the 
> light, respiring and giving off carbon dioxide, which would dissolve in the 
> water, making it more acidic. 
> 
> Cheers, 
> 
> Peter O'Byrne 
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