Have you tried selecting everything, then exporting the whole catalog
to a new catalog?
How large are the master files? What kind of files are they ... raw,
JPEG, TIFF, PSD?
Are the masters on the same volume as the catalog folder? How much
free space is on the volume?
How big is the Camera Raw cache? (LR Prefernces- file handling tab)

My "in progress" catalog has 78,000+ photos in it now. The .LRCAT file
is about 1.5G in size. It's on the internal drive of my MacBook Pro
13" (2.4Ghz, 8G RAM, running Mac OS X "Lion", with about 130G free on
the startup volume and a 10G camera raw cache). Takes about minute to
load.

-- 
Godfrey
  godfreydigiorgi.posterous.com

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